中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A comparative study of thermolysis characteristics and kinetics of seaweeds and fir wood

文献类型:期刊论文

作者Wang, J; Wang, G; Zhang, MX; Chen, MQ; Li, DM; Min, FF; Chen, MG; Zhang, SP; Ren, ZW; Yan, YJ
刊名PROCESS BIOCHEMISTRY
出版日期2006-08-01
卷号41期号:8页码:1883-1886
关键词Biomass Seaweed Land Plants Thermal Analysis Kinetics Themolysis
ISSN号1359-5113
DOI10.1016/j.procbio.2006.03.018
文献子类Article
英文摘要Thermal analysis and thermolysis kinetics of three kinds of seaweeds and fir wood (M. glyptostriboides Huet Cheng), a kind of typical land plant, had been conducted. The results showed that thermal stability follows the order of Grateloupia filicina < Ulva lactuca < Dictyopteris divaricata < fir wood. A notable difference on heat flow between seaweeds and fir wood during thermolysis was that the former were mainly connected with exothermic processes at relatively lower temperature regimes. while the latter was connected with an apparent endotherm at a relatively higher temperature regime followed by a maximum exothermic peak. This suggested that the heat coupling might be realized if co-thermolysis of seaweeds and fir wood were carried out. The main devolatilization phase of each seaweed could be described by Avrami-Erofeev equation, which indicated that thermolysis of seaweeds follows the mechanism of random nucleation and nuclei growth, whereas that of fir wood by Z-L-T equation and its thermolysis mechanism was three-dimensional diffusion. The activation energies calculated for both seaweeds and fir wood increase as conversion increases. However, those for the former have wider distribution. (c) 2006 Elsevier Ltd. All rights reserved.; Thermal analysis and thermolysis kinetics of three kinds of seaweeds and fir wood (M. glyptostriboides Huet Cheng), a kind of typical land plant, had been conducted. The results showed that thermal stability follows the order of Grateloupia filicina < Ulva lactuca < Dictyopteris divaricata < fir wood. A notable difference on heat flow between seaweeds and fir wood during thermolysis was that the former were mainly connected with exothermic processes at relatively lower temperature regimes. while the latter was connected with an apparent endotherm at a relatively higher temperature regime followed by a maximum exothermic peak. This suggested that the heat coupling might be realized if co-thermolysis of seaweeds and fir wood were carried out. The main devolatilization phase of each seaweed could be described by Avrami-Erofeev equation, which indicated that thermolysis of seaweeds follows the mechanism of random nucleation and nuclei growth, whereas that of fir wood by Z-L-T equation and its thermolysis mechanism was three-dimensional diffusion. The activation energies calculated for both seaweeds and fir wood increase as conversion increases. However, those for the former have wider distribution. (c) 2006 Elsevier Ltd. All rights reserved.
学科主题Biochemistry & Molecular Biology ; Biotechnology & Applied Microbiology ; Engineering, Chemical
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语种英语
WOS记录号WOS:000238398000024
公开日期2010-12-24
源URL[http://ir.qdio.ac.cn/handle/337002/5953]  
专题海洋研究所_实验海洋生物学重点实验室
作者单位1.Anhui Univ Sci & Technol, Dept Chem Engn, Anhua 232001, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
3.Anhui Univ Sci & Technol, Dept Mat Engn, Anhua 232001, Peoples R China
4.E China Univ Sci & Technol, Dept Chem Engn Energy Recourses, Shanghai 200237, Peoples R China
5.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wang, J,Wang, G,Zhang, MX,et al. A comparative study of thermolysis characteristics and kinetics of seaweeds and fir wood[J]. PROCESS BIOCHEMISTRY,2006,41(8):1883-1886.
APA Wang, J.,Wang, G.,Zhang, MX.,Chen, MQ.,Li, DM.,...&Yan, YJ.(2006).A comparative study of thermolysis characteristics and kinetics of seaweeds and fir wood.PROCESS BIOCHEMISTRY,41(8),1883-1886.
MLA Wang, J,et al."A comparative study of thermolysis characteristics and kinetics of seaweeds and fir wood".PROCESS BIOCHEMISTRY 41.8(2006):1883-1886.

入库方式: OAI收割

来源:海洋研究所

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