Interaction of gas phase atomic hydrogen with Pt(111): Direct evidence for the formation of bulk hydrogen species
文献类型：期刊论文
| 作者 | Jiang ZhiQuan; Huang WeiXin; Bao Xinhe |
| 刊名 | science in china series b-chemistry
 |
| 出版日期 | 2007-02-01 |
| 卷号 | 50期号:1页码:91-96 |
| 关键词 | Pt(111) surface bulk H species thermal desorption spectroscopy |
| 产权排序 | 2;3 |
| 通讯作者 | 包信和 |
| 英文摘要 | employing hot tungsten filament to thermal dissociate molecular hydrogen, we generated gas phase atomic hydrogen under ultra-high vacuum (uhv) conditions and investigated its interaction with pt(111) surface. thermal desorption spectroscopy (tds) results demonstrate that adsorption of molecular hydrogen on pt(111) forms surface h-ad species whereas adsorption of atomic hydrogen forms not only surface h-ad species but also bulk h-ad species. bulk h-ad species is more thermal-unstable than surface h-ad species on pt(111), suggesting that bulk h-ad species is more energetic. this kind of weakly-adsorbed bulk h-ad species might be the active hydrogen species in the pt-catalyzed hydrogenation reactions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | carbon bond activation ; surface-bound-h ; catalytic-hydrogenation ; model catalysts ; ni(100) surface ; cyclopropane ; ni(111) ; chemistry ; hydrocarbons ; reactivity |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000245148000014 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/99237]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang ZhiQuan,Huang WeiXin,Bao Xinhe. Interaction of gas phase atomic hydrogen with Pt(111): Direct evidence for the formation of bulk hydrogen species[J]. science in china series b-chemistry,2007,50(1):91-96. |
| APA | Jiang ZhiQuan,Huang WeiXin,&Bao Xinhe.(2007).Interaction of gas phase atomic hydrogen with Pt(111): Direct evidence for the formation of bulk hydrogen species.science in china series b-chemistry,50(1),91-96. |
| MLA | Jiang ZhiQuan,et al."Interaction of gas phase atomic hydrogen with Pt(111): Direct evidence for the formation of bulk hydrogen species".science in china series b-chemistry 50.1(2007):91-96. |
入库方式： OAI收割
来源：大连化学物理研究所
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