Highly stable PtRuTiOx/C anode electrocatalyst for direct methanol fuel cells
文献类型：期刊论文
| 作者 | Tian, Juan; Sun, Gongquan; Jiang, Luhua; Yan, Shiyou; Mao, Qing; Xin, Qin |
| 刊名 | electrochemistry communications
 |
| 出版日期 | 2007-04-01 |
| 卷号 | 9期号:4页码:563-568 |
| 关键词 | direct methanol fuel cell PtRu electrocatalyst titanium oxide thermal treatment durability |
| 产权排序 | 1;1 |
| 通讯作者 | 孙公权 |
| 英文摘要 | in the present investigation, ptrutiox/c electrocatalyst was prepared by a modified polyol synthesis method and the as-prepared electrocatalyst was treated under the reductive atmosphere (30 vol% h-2 in ar) at 500 degrees c for 2 h (denoted as ptrutiox/c-500) to enhance the interaction between the metal particles and the support. for comparison, the commercial ptru/c electrocatalyst was also treated by the same procedure as ptrutiox/c (denoted as ptru/c-500). transmission electron microscopy results indicated that ptrutiox/c electrocatalyst exhibited not only a uniform dispersion and narrow size distribution with a smaller particle size, but also excellent stability during the thermal treatment. in contrast, the commercial ptru/c electrocatalyst is not stable during the thermal treatment and the metal particles greatly agglomerated. the results of co-stripping voltammetry, single direct methanol fuel cell tests and life-time test jointly showed that ptrutiox/c-500 had better durability than commercial ptru/c while keeping a desirable activity toward methanol electro-oxidation, which may be attributed to the addition of titanium oxide that improved the interaction between noble metal particles and the support. (c) 2006 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | electrochemistry |
| 研究领域[WOS] | electrochemistry |
| 关键词[WOS] | catalysts ; electrooxidation ; performance ; degradation ; precursors ; oxidation ; tio2 |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000246053700007 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/99263]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Direct Alcohol Fuel Cell Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian, Juan,Sun, Gongquan,Jiang, Luhua,et al. Highly stable PtRuTiOx/C anode electrocatalyst for direct methanol fuel cells[J]. electrochemistry communications,2007,9(4):563-568. |
| APA | Tian, Juan,Sun, Gongquan,Jiang, Luhua,Yan, Shiyou,Mao, Qing,&Xin, Qin.(2007).Highly stable PtRuTiOx/C anode electrocatalyst for direct methanol fuel cells.electrochemistry communications,9(4),563-568. |
| MLA | Tian, Juan,et al."Highly stable PtRuTiOx/C anode electrocatalyst for direct methanol fuel cells".electrochemistry communications 9.4(2007):563-568. |
入库方式： OAI收割
来源：大连化学物理研究所
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