Synthesis and structural characterization of ruthenium(II) complexes bearing phosphine-pyrazolyl based tripod ligands
文献类型：期刊论文
| 作者 | Tan, Weiqiang; Zhao, Xiaodan; Yu, Zhengkun |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 2007-11-15 |
| 卷号 | 692期号:24页码:5395-5402 |
| 关键词 | tripod ligands pyrazolyl phosphine ruthenium(II) p-cymene |
| 产权排序 | 1;1 |
| 通讯作者 | 余正坤 |
| 英文摘要 | phosphine-pyrazolyl based tripod ligands roch2c(ch(2)pz)(2)(ch2pph2) ( r = h, me, allyl; pz = pyrazol-1-yl) were e. ciently synthesized and characterized. reactions of these ligands with [ru(eta(6)-p-cymene)cl-2](2) afforded complexes of the type [ru(eta(6)-p-cymene) cl-2](l) (6-8) in which the ligands exhibit kappa(1)-p-coordination to the metal center. complex [ru(eta(6)-p-cymene)cl-2{ph2pch2c( ch2oh)(ch(2)pz)(2)}] (6) underwent chloride-dissociation in ch2cl2/mecn to give complex [rucl(eta(6)-p-cymene){kappa(2)(p,n)-ph2pch2c( ch2oh)(ch(2)pz)(2)}][cl] (9). complexes 6-9 demonstrated poor to moderate catalytic activity in the transfer hydrogenation of acetophenone. all these complexes were fully characterized by analytical and spectroscopic methods and their molecular structures were determined by x-ray crystallographic study. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | catalytic-activity ; coordination chemistry ; transfer hydrogenation ; polyphosphine ligands ; d(8)-metal complexes ; rhodium complexes ; chelate ligands ; reactivity ; arene ; cyclopentadienyl |
| 收录类别 | SCI ; IC ; CCR |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000253488400010 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/99491]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tan, Weiqiang,Zhao, Xiaodan,Yu, Zhengkun. Synthesis and structural characterization of ruthenium(II) complexes bearing phosphine-pyrazolyl based tripod ligands[J]. journal of organometallic chemistry,2007,692(24):5395-5402. |
| APA | Tan, Weiqiang,Zhao, Xiaodan,&Yu, Zhengkun.(2007).Synthesis and structural characterization of ruthenium(II) complexes bearing phosphine-pyrazolyl based tripod ligands.journal of organometallic chemistry,692(24),5395-5402. |
| MLA | Tan, Weiqiang,et al."Synthesis and structural characterization of ruthenium(II) complexes bearing phosphine-pyrazolyl based tripod ligands".journal of organometallic chemistry 692.24(2007):5395-5402. |
入库方式： OAI收割
来源：大连化学物理研究所
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