Structure analysis on complexes of xanthone glycosides and metal ions using Electrospray ionization tandem mass Spectrometry
文献类型：期刊论文
| 作者 | Sun, Y. G.; Zhang, X.; Wang, L.; Xue, X. Y.; Xiao, H. B.; Liang, X. M. |
| 刊名 | polish journal of chemistry
 |
| 出版日期 | 2007-10-01 |
| 卷号 | 81期号:10页码:1687-1700 |
| 关键词 | electrospray ionization xanthone glycosides metal complexes coordination sites MS/MS spectrum |
| 产权排序 | 1;1 |
| 通讯作者 | 梁鑫淼 |
| 英文摘要 | the structure and fragmentation mechanism of metal (mn(ii), al(iii) and cu(ii)) complexes of xanthone glycosides as well as metal coordination sites were investigated by electrospray ionization tandem mass spectrometry. four mn(ii) complexes of xanthone glycoside with different stoichiometric ratios were observed from swertianin 7-o-rhamnosyl(l -> 2)xyloside, swertianin 7-o-xylosy](1 -> 2)xyloside and swertianolin, while only two complexes were formed for 3,7,8-trimethoxy-1-o-primeverosyloxanthone, 2,3,5-trimethoxy-1-o-primeverosyloxanthone and 2,3,4,5-tetramethoxy-1-o-primeverosyloxanthone, respectively. for xanthone glycoside-cu(ii) complexes, three complexes with different stoichiometric ratios were observed from swertianin 7-o-rhamnosyl(l -> 2)xyloside, swertianin 7-o-xylosyl(l -> 2) xyloside and swertianolin, but only one al(iii) complexes were formed for above three xanthone glycosides. based on the analysis of metal complexes by tandem mass spectrometry, a fragmentation mechanism for 1:1 swertianin 7-o-rhamnosyl(l -> 2)xyloside-mn(ii) complex was proposed and the structures of four swertianin 7-o-rhamnosyl(1 -> 2)xyloside-mn(ii) complexes were interpreted. in addition, the hydroxyl groups in the oligosaccharide chains, the hydroxyl groups substituted at c-1 and c-8, and the carbonyl group in the c-ring of the aglycone, were proved to be the dominant coordination sites in the xanthone glycosidemetal complexes. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | collisionally activated dissociation ; binding selectivities ; flavonoid glycosides ; trap ; identification ; antibiotics ; chelation |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000250769800001 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/99535]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Y. G.,Zhang, X.,Wang, L.,et al. Structure analysis on complexes of xanthone glycosides and metal ions using Electrospray ionization tandem mass Spectrometry[J]. polish journal of chemistry,2007,81(10):1687-1700. |
| APA | Sun, Y. G.,Zhang, X.,Wang, L.,Xue, X. Y.,Xiao, H. B.,&Liang, X. M..(2007).Structure analysis on complexes of xanthone glycosides and metal ions using Electrospray ionization tandem mass Spectrometry.polish journal of chemistry,81(10),1687-1700. |
| MLA | Sun, Y. G.,et al."Structure analysis on complexes of xanthone glycosides and metal ions using Electrospray ionization tandem mass Spectrometry".polish journal of chemistry 81.10(2007):1687-1700. |
入库方式： OAI收割
来源：大连化学物理研究所
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