Low-temperature heat capacities and thermodynamic properties of hydrated sodium cupric arsenate [NaCuASO(4) center dot 1.5H2O(s)]
文献类型：期刊论文
| 作者 | Chen Jing-tao; Di You-ying; Tan Zhi-cheng; Sun Li-xian |
| 刊名 | chemical research in chinese universities
 |
| 出版日期 | 2007-09-01 |
| 卷号 | 23期号:5页码:574-578 |
| 关键词 | NaCuAsO4 center dot 1. 5H(2)O(S) adiabatic calorimetry heat capacity thermodynamic function dehydration process |
| ISSN号 | 1005-9040 |
| 产权排序 | 3;3 |
| 通讯作者 | di you-ying |
| 英文摘要 | low-temperature heat capacities of the solid compound nacuaso4 center dot 1.5 h2o (s) were measured using a precision automated adiabatic calorimeter over a temperature range of t = 78 k to t = 390 k. a dehydration process occurred in the temperature range of t = 368-374 k. the peak temperature of the dehydration was observed to be t-d = ( 371.828 +/- 0.146) k by means of the heat-capacity measurement. the molar enthalpy and entropy of the dehydration were delta h-d(m) = (18.571 +/- 0.142) kj/mol and delta s-d(m) = (49.946 +/- 0.415) j/( k center dot mol), respectively. the experimental values of heat capacities for the solid( i) and the solid-liquid mixture( 11) were respectively fitted to two polynomial equations by the least square method. the smoothed values of the molar heat capacities and the fundamental thermodynamic functions of the sample relative to the standard reference temperature 298.15 k were tabulated at an interval of 5 k. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000250324000020 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/99625]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Peoples R China 2.Shaanxi Educ Coll, Dept Chem, Xian 710061, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen Jing-tao,Di You-ying,Tan Zhi-cheng,et al. Low-temperature heat capacities and thermodynamic properties of hydrated sodium cupric arsenate [NaCuASO(4) center dot 1.5H2O(s)][J]. chemical research in chinese universities,2007,23(5):574-578. |
| APA | Chen Jing-tao,Di You-ying,Tan Zhi-cheng,&Sun Li-xian.(2007).Low-temperature heat capacities and thermodynamic properties of hydrated sodium cupric arsenate [NaCuASO(4) center dot 1.5H2O(s)].chemical research in chinese universities,23(5),574-578. |
| MLA | Chen Jing-tao,et al."Low-temperature heat capacities and thermodynamic properties of hydrated sodium cupric arsenate [NaCuASO(4) center dot 1.5H2O(s)]".chemical research in chinese universities 23.5(2007):574-578. |
入库方式： OAI收割
来源：大连化学物理研究所
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