中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Prussian Blue electrodepo sited on MWNTs-PANI hybrid composites for H2O2 detection

文献类型:期刊论文

作者Zou, Yongjin; Sun, Lixian; Xu, Fen
刊名talanta
出版日期2007-04-30
卷号72期号:2页码:437-442
关键词Prussian Blue multi-walled carbon nanombes polyaniline hybrid composite H2O2
ISSN号0039-9140
产权排序1;1
通讯作者孙立贤
英文摘要a prussian blue (pb)/polyaniline (pani)/multi-walled carbon nanotubes (mwnts) composite film was fabricated by step-by-step electrode-position on glassy carbon electrode (gce). the electrode prepared exhibits enhanced electrocatalytic behavior and good stability for detection of h2o2 at an applied potential of 0.0 v the effects of mwnts thickness, electrodeposition time of pani and rotating rate on the current response of the composite modified electrode toward h2o2 were optimized to obtain the maximal sensitivity. a linear range from 8 x 10(-9) to 5 x 10(-6) m for h2o2 detection has been observed at the pb/pani/mwnts modified gce with a correlation coefficient of 0.997. the detection limit is 5 x 10(-9) m on signal-to-noise ratio of 3. to the best of our knowledge, this is the lowest detection limit for h2o2 detection. the electrode also shows high sensitivity (526.43 mu a mu m-1 cm(-2)) for h2o2 detection which is more than three orders of magnitude higher than the reported. (c) 2006 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, analytical
研究领域[WOS]chemistry
关键词[WOS]nanotube-modified electrodes ; walled carbon nanotubes ; hydrogen-peroxide ; direct electrochemistry ; amperometric biosensor ; glucose ; sensors ; enzyme ; immobilization ; nanoelectrode
收录类别SCI
原文出处true
语种英语
WOS记录号WOS:000246321200016
公开日期2010-11-30
源URL[http://159.226.238.44/handle/321008/99639]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zou, Yongjin,Sun, Lixian,Xu, Fen. Prussian Blue electrodepo sited on MWNTs-PANI hybrid composites for H2O2 detection[J]. talanta,2007,72(2):437-442.
APA Zou, Yongjin,Sun, Lixian,&Xu, Fen.(2007).Prussian Blue electrodepo sited on MWNTs-PANI hybrid composites for H2O2 detection.talanta,72(2),437-442.
MLA Zou, Yongjin,et al."Prussian Blue electrodepo sited on MWNTs-PANI hybrid composites for H2O2 detection".talanta 72.2(2007):437-442.

入库方式: OAI收割

来源:大连化学物理研究所

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