Low-temperature heat capacities and standard molar enthalpy of formation of the complex Zn(Val)SO4 center dot H2O(s) Val=L-alpha-valine)
文献类型：期刊论文
| 作者 | Di, Y. Y.; Tan, Z. C.; Li, L. W.; Gao, S. L.; Sun, L. X. |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2007 |
| 卷号 | 87期号:2页码:545-551 |
| 关键词 | adiabatic calorimetry isoperibol solution-reaction calorimetry standard molar enthalpy of formation UV/Vis spectroscopy Zn(Val)SO4 center dot H2O(s) |
| ISSN号 | 1388-6150 |
| 产权排序 | 2;1 |
| 通讯作者 | 邸友莹 |
| 英文摘要 | low-temperature heat capacities of a solid complex zn(val)so4 center dot h2o(s) were measured by a precision automated adiabatic calorimeter over the temperature range between 78 and 373 k. the initial dehydration temperature of the coordination compound was determined to be, t (d)=327.05 k, by analysis of the heat-capacity curve. the experimental values of molar heat capacities were fitted to a polynomial equation of heat capacities (c (p,m)) with the reduced temperatures (x), [x=f (t)], by least square method. the polynomial fitted values of the molar heat capacities and fundamental thermodynamic functions of the complex relative to the standard reference temperature 298.15 k were given with the interval of 5 k. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000244313900042 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/99673]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China 3.NW Univ Xian, Dept Chem, Xian 710069, Peoples R China |
| 推荐引用方式 GB/T 7714 | Di, Y. Y.,Tan, Z. C.,Li, L. W.,et al. Low-temperature heat capacities and standard molar enthalpy of formation of the complex Zn(Val)SO4 center dot H2O(s) Val=L-alpha-valine)[J]. journal of thermal analysis and calorimetry,2007,87(2):545-551. |
| APA | Di, Y. Y.,Tan, Z. C.,Li, L. W.,Gao, S. L.,&Sun, L. X..(2007).Low-temperature heat capacities and standard molar enthalpy of formation of the complex Zn(Val)SO4 center dot H2O(s) Val=L-alpha-valine).journal of thermal analysis and calorimetry,87(2),545-551. |
| MLA | Di, Y. Y.,et al."Low-temperature heat capacities and standard molar enthalpy of formation of the complex Zn(Val)SO4 center dot H2O(s) Val=L-alpha-valine)".journal of thermal analysis and calorimetry 87.2(2007):545-551. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。