Direct catalytic asymmetric aldol reactions on chiral catalysts assembled in the interface of emulsion droplets
文献类型：期刊论文
| 作者 | Zhong, Lin; Gao, Qiang; Gao, Jinbo; Xiao, Jianliang; Li, Can |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2007-09-10 |
| 卷号 | 250期号:2页码:360-364 |
| 关键词 | aldol reaction asymmetric synthesis emulsion catalysis interface |
| 产权排序 | 1;1 |
| 通讯作者 | 李灿 |
| 英文摘要 | an amphiphilic proline-based organocatalyst was assembled on the interface of water and oil, resulting in a w/o emulsion. the chiral catalyst in emulsion significantly enhances the reactivity and stereoselectivity of the direct asymmetric aldol reactions, which can be attributed mainly to the larger interfacial surface area and uniformly distributed catalyst molecules in the interface of the emulsion droplets. (c) 2007 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | diels-alder reaction ; amino-acid ; cationic surfactants ; reaction media ; aqueous-media ; lewis-acid ; water ; organocatalyst ; reduction ; ketones |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000249564600018 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/99679]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England |
| 推荐引用方式 GB/T 7714 | Zhong, Lin,Gao, Qiang,Gao, Jinbo,et al. Direct catalytic asymmetric aldol reactions on chiral catalysts assembled in the interface of emulsion droplets[J]. journal of catalysis,2007,250(2):360-364. |
| APA | Zhong, Lin,Gao, Qiang,Gao, Jinbo,Xiao, Jianliang,&Li, Can.(2007).Direct catalytic asymmetric aldol reactions on chiral catalysts assembled in the interface of emulsion droplets.journal of catalysis,250(2),360-364. |
| MLA | Zhong, Lin,et al."Direct catalytic asymmetric aldol reactions on chiral catalysts assembled in the interface of emulsion droplets".journal of catalysis 250.2(2007):360-364. |
入库方式： OAI收割
来源：大连化学物理研究所
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