Production of hydrogen peroxide by the reaction of hydroxylamine and molecular oxygen over activated carbons
文献类型：期刊论文
| 作者 | Song, Wei; Li, Juan; Liu, Junlong; Shen, Wenjie |
| 刊名 | catalysis communications
 |
| 出版日期 | 2008-03-20 |
| 卷号 | 9期号:5页码:831-836 |
| 关键词 | in situ production hydrogen peroxide hydroxylamine oxygen activated carbon |
| 产权排序 | 1;1 |
| 通讯作者 | 申文杰 |
| 英文摘要 | in situ production of hydrogen peroxide was achieved by the reaction of hydroxylamine and molecular oxygen over reusable activated carbon catalysts at ambient temperature with environmentally benign by-products (nitrogen and water). the yield of hydrogen peroxide was about 46% with the concentration of 0.39 wt% (114 mmol/l). temperature-programmed desorption analysis and fourier transformation infrared spectroscopy revealed that the oxygen-containing species, especially quinone/semiquinone-like structures, on the surface of activated carbon played a crucial role in the generation of h2o2, probably through the effective activation of oxygen molecule. (c) 2007 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | in-situ generation ; pd/al2o3 catalyst ; nonaqueous medium ; reduction ; oxidation ; dioxygen ; complexes ; chemistry ; membrane ; benzene |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000253450900051 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/99945]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Wei,Li, Juan,Liu, Junlong,et al. Production of hydrogen peroxide by the reaction of hydroxylamine and molecular oxygen over activated carbons[J]. catalysis communications,2008,9(5):831-836. |
| APA | Song, Wei,Li, Juan,Liu, Junlong,&Shen, Wenjie.(2008).Production of hydrogen peroxide by the reaction of hydroxylamine and molecular oxygen over activated carbons.catalysis communications,9(5),831-836. |
| MLA | Song, Wei,et al."Production of hydrogen peroxide by the reaction of hydroxylamine and molecular oxygen over activated carbons".catalysis communications 9.5(2008):831-836. |
入库方式： OAI收割
来源：大连化学物理研究所
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