Super-microporous organosilicas synthesized from well-defined nanobuilding units
文献类型：期刊论文
| 作者 | Zhang, Lei1; Yang, Qihua1; Yang, Hengquan1; Liu, Jian1; Xin, Hongchuan1; Mezari, Brahim2; Magusin, Pieter C. M. M.2; Abbenhuis, Hendrikus C. L.2; van Santen, Rutger A.2; Li, Can1 |
| 刊名 | journal of materials chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 18期号:4页码:450-457 |
| 产权排序 | 1;1 |
| 通讯作者 | 杨启华 ; 李灿 |
| 英文摘要 | super-microporous organosilica with bridging ethylene and pendant vinyl groups has been synthesized by assembling predefined nanobuilding block polyhedral oligomeric silsesquioxanes (poss) with nonionic surfactant brij-76 as the template. the material shows wormhole-like super-micropores with uniform size of 1.9 nm, high bet surface area of 872 m(2) g(-1) and pore volume of 0.52 cm(3) g(-1). ir and nmr results show that the bridging ethylene, the pendant vinyl groups and the double-4-membered ring structure were successfully transferred from the building blocks to the super-microporous organosilica material. the material shows high hydrothermal stability and can further react with br-2. the advantage of the present approach lies in that the relative contents and proximity of the different organic functionalities in the final material can be well controlled through the starting nanobuilding blocks. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; materials science |
| 关键词[WOS] | periodic mesoporous organosilicas ; inorganic nanocomposite materials ; molecular-scale periodicity ; hydrothermal stability ; surfactant mesophases ; nanoporous materials ; hybrid materials ; silica spheres ; organic groups ; aluminosilicate |
| 收录类别 | SCI |
| 原文出处 | true |
| 语种 | 英语 |
| WOS记录号 | WOS:000252232700011 |
| 公开日期 | 2010-11-30 |
| 源URL | [http://159.226.238.44/handle/321008/100157]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands |
| 推荐引用方式 GB/T 7714 | Zhang, Lei,Yang, Qihua,Yang, Hengquan,et al. Super-microporous organosilicas synthesized from well-defined nanobuilding units[J]. journal of materials chemistry,2008,18(4):450-457. |
| APA | Zhang, Lei.,Yang, Qihua.,Yang, Hengquan.,Liu, Jian.,Xin, Hongchuan.,...&Li, Can.(2008).Super-microporous organosilicas synthesized from well-defined nanobuilding units.journal of materials chemistry,18(4),450-457. |
| MLA | Zhang, Lei,et al."Super-microporous organosilicas synthesized from well-defined nanobuilding units".journal of materials chemistry 18.4(2008):450-457. |
入库方式： OAI收割
来源：大连化学物理研究所
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