Selective activation of c-h bond into c=0 bond of phenols in para-position via aerobic oxidation
文献类型：期刊论文
| 作者 | Yang, Shilei1; Xu, Guoqiang1; Shi, Song2; Xin, Hongchuan1; Gao, Jin2; An, Zengjian1 |
| 刊名 | Catalysis communications
 |
| 出版日期 | 2019-04-01 |
| 卷号 | 123页码:105-108 |
| 关键词 | Selective activation C-h bond C=o bond Phenols Aerobic oxidation |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2019.02.017 |
| 通讯作者 | Xin, hongchuan(xinhc@qibebt.ac.cn) ; Gao, jin(gaojin@dicp.ac.cn) ; An, zengjian(anzj@qibebt.ac.cn) |
| 英文摘要 | An efficient method for the oxidation of phenols to 1,4-benzoquinones catalyzed by cuprous(i) chloride was achieved in a solution of acetonitrile and water using molecular dioxygen as an oxidant. particularly, the inert phenols, such as phenol and mono-alkyl substituted phenols, were effectively oxidized to 1,4-benzoquinones via the selective activation of c-h bond in para-position into c=o bond under mild conditions. the catalyst shows high activity for unsubstituted or alkyl substituted phenols, but no effect on substituted phenols with electron withdrawing groups. this study offers an aerobic method for the selective oxidation of aromatic phenols to 1,4-benzoquinones. |
| WOS关键词 | AQUEOUS HYDROGEN-PEROXIDE ; COPPER(II) CHLORIDE ; H2O2-BASED OXIDATION ; CATALYZED OXIDATION ; 2,3,6-TRIMETHYLPHENOL ; 2,3,5-TRIMETHYLBENZOQUINONE ; TRIMETHYL-1,4-BENZOQUINONE ; 2,3,5-TRIMETHYLPHENOL ; BENZOQUINONES ; ALKYLPHENOLS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000463124300021 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372661 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Xin, Hongchuan; Gao, Jin; An, Zengjian |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Shilei,Xu, Guoqiang,Shi, Song,et al. Selective activation of c-h bond into c=0 bond of phenols in para-position via aerobic oxidation[J]. Catalysis communications,2019,123:105-108. |
| APA | Yang, Shilei,Xu, Guoqiang,Shi, Song,Xin, Hongchuan,Gao, Jin,&An, Zengjian.(2019).Selective activation of c-h bond into c=0 bond of phenols in para-position via aerobic oxidation.Catalysis communications,123,105-108. |
| MLA | Yang, Shilei,et al."Selective activation of c-h bond into c=0 bond of phenols in para-position via aerobic oxidation".Catalysis communications 123(2019):105-108. |
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来源：大连化学物理研究所
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