Triplet energy transfer from cspbbr3 nanocrystals enabled by quantum confinement
文献类型：期刊论文
| 作者 | Luo, Xiao1; Lai, Runchen1; Li, Yulu1; Han, Yaoyao1,2; Liang, Guijie1,3; Liu, Xue1; Ding, Tao1; Wang, Junhui1; Wu, Kaifeng1 |
| 刊名 | Journal of the american chemical society
 |
| 出版日期 | 2019-03-13 |
| 卷号 | 141期号:10页码:4186-4190 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.8b13180 |
| 通讯作者 | Wu, kaifeng(kwu@dicp.ac.cn) |
| 英文摘要 | The spectral properties of lead halide perovskite nanocrystals (ncs) can be engineered by tuning either their sizes via the quantum confinement effect or their compositions using anion and/or cation exchange. to date, the latter is more frequently adopted, primarily because of the ease of ion exchange for lead halide perovskites, making the quantum confinement effect seemingly redundant for perovskite ncs. here we report that quantum confinement is required for triplet energy transfer (tet) from perovskite ncs to polycyclic aromatic hydrocarbons (pahs). static and transient spectroscopy measurements on cspbbr3 nc-pyrene hybrids showed that efficient tet occurred only for small-sized, quantum-confined cspbbr3 ncs. the influences of the size-dependent driving force and spectral overlap on the tet rate were found to be negligible. instead, the tet rate scaled linearly with carrier probability density at the nc surface, consistent with a dexter-type tet mechanism requiring wave function exchange between the nc donors and pyrene acceptors. efficient tet funnels the excitation energy generated in strongly light-absorbing perovskite ncs into long-lived triplets in pahs, which may find broad applications such as photon upconversion and photoredox catalysis. |
| WOS关键词 | HALIDE PEROVSKITES CSPBX3 ; PHOTON UP-CONVERSION ; ELECTRON-TRANSFER ; ANION-EXCHANGE ; SEMICONDUCTOR ; DOTS ; TRANSMITTER ; BR ; CL |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000461537700004 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372706 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Wu, Kaifeng |
| 作者单位 | 1.Chinese Acad Sci, Ctr Energy & Environm Mat, Dalian Inst Chem Phys, State Key Lab Mol React Dynam & Dynam Res, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Hubei Univ Arts & Sci, Hubei Key Lab Low Dimens Optoelect Mat & Devices, Xiangyang 441053, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Xiao,Lai, Runchen,Li, Yulu,et al. Triplet energy transfer from cspbbr3 nanocrystals enabled by quantum confinement[J]. Journal of the american chemical society,2019,141(10):4186-4190. |
| APA | Luo, Xiao.,Lai, Runchen.,Li, Yulu.,Han, Yaoyao.,Liang, Guijie.,...&Wu, Kaifeng.(2019).Triplet energy transfer from cspbbr3 nanocrystals enabled by quantum confinement.Journal of the american chemical society,141(10),4186-4190. |
| MLA | Luo, Xiao,et al."Triplet energy transfer from cspbbr3 nanocrystals enabled by quantum confinement".Journal of the american chemical society 141.10(2019):4186-4190. |
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来源：大连化学物理研究所
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