中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Ultrafast dynamics of water molecules excited to electronic (f)over-tilde states: a time-resolved photoelectron spectroscopy study

文献类型:期刊论文

作者Yang, Dong-yuan1,2; Min, Yan-jun1,2; Chen, Zhen1,2; He, Zhi-gang1; Chen, Zhi-chao1; Yuan, Kai-jun1; Dai, Dong-xu1; Wu, Guo-rong1; Yang, Xue-ming1
刊名Chinese journal of chemical physics
出版日期2019-02-01
卷号32期号:1页码:53-58
关键词Photoelectron spectrum Pump/probe Femtosecond time-resolved sprctra
ISSN号1674-0068
DOI10.1063/1674-0068/cjcp1811243
通讯作者Wu, guo-rong(wugr@dicp.ac.cn)
英文摘要The ultrafast dynamics of water molecules excited to the two (f) over tilde states is studied by combining two-photon excitation and time-resolved photoelectron imaging techniques. the lifetimes of the (f) over tilde (1)a(1) and (f) over tilde b-1(1) states of h2o (d2o) were derived to be 1.0 +/- 0.3 (1.9 +/- 0.4) and 10 +/- 3 (30 +/- 10) ps, respectively. we propose that the (f) over tilde (1)a(1) state mainly decays through the (d) over tilde state, due to the nonadiabatic coupling between them, while the (f) over tilde b-1(1) state decays through the (f) over tilde (1)a(1) state via coriolis interaction.
WOS关键词PHOTODISSOCIATION DYNAMICS ; PREDISSOCIATION-DYNAMICS ; ABSORPTION-BAND ; H2O ; D2O ; (C)OVER-TILDE ; DISSOCIATION ; IONIZATION ; SPECTRA
WOS研究方向Physics
WOS类目Physics, Atomic, Molecular & Chemical
语种英语
WOS记录号WOS:000461781200006
出版者CHINESE PHYSICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2372709
专题大连化学物理研究所
通讯作者Wu, Guo-rong
作者单位1.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Yang, Dong-yuan,Min, Yan-jun,Chen, Zhen,et al. Ultrafast dynamics of water molecules excited to electronic (f)over-tilde states: a time-resolved photoelectron spectroscopy study[J]. Chinese journal of chemical physics,2019,32(1):53-58.
APA Yang, Dong-yuan.,Min, Yan-jun.,Chen, Zhen.,He, Zhi-gang.,Chen, Zhi-chao.,...&Yang, Xue-ming.(2019).Ultrafast dynamics of water molecules excited to electronic (f)over-tilde states: a time-resolved photoelectron spectroscopy study.Chinese journal of chemical physics,32(1),53-58.
MLA Yang, Dong-yuan,et al."Ultrafast dynamics of water molecules excited to electronic (f)over-tilde states: a time-resolved photoelectron spectroscopy study".Chinese journal of chemical physics 32.1(2019):53-58.

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来源:大连化学物理研究所

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