Toward fundamentals of confined electrocatalysis in nanoscale reactors
文献类型：期刊论文
| 作者 | Li, Haobo1; Guo, Chenxi1; Fu, Qiang2; Xiao, Jianping1,2 |
| 刊名 | Journal of physical chemistry letters
 |
| 出版日期 | 2019-02-07 |
| 卷号 | 10期号:3页码:533-539 |
| ISSN号 | 1948-7185 |
| DOI | 10.1021/acs.jpclett.8b03448 |
| 通讯作者 | Xiao, jianping(xiao@dicp.ac.cn) |
| 英文摘要 | A number of experiments have demonstrated that electrochemical reactions are feasible in confined nanoscale reactors, while what the fundamentals of confined electrochemistry are is not clear. using first-principles calculations and electrochemical modeling, we find that the capacitance in the confined nanoscale reactors can be significantly enhanced, compared to an open electrode interface, essentially promoting the electrochemical reactions and charge transfer efficiency in nanoscale reactors. more importantly, this is a general character, as found in a variety of electrochemical and thermochemical reactions. at the end, we use the recently defined new concept of "confinement energy" for understanding the nature of confined electrochemistry from both thermochemical and electrochemical points of view. |
| WOS关键词 | GRAPHENE FILMS ; CATALYSIS ; POINTS ; SIZE |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000458704800035 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372791 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Xiao, Jianping |
| 作者单位 | 1.Westlake Univ, Sch Sci, Westlake Inst Adv Study, Inst Nat Sci, Hangzhou 310024, Zhejiang, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Zhongshan Rd 457, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Haobo,Guo, Chenxi,Fu, Qiang,et al. Toward fundamentals of confined electrocatalysis in nanoscale reactors[J]. Journal of physical chemistry letters,2019,10(3):533-539. |
| APA | Li, Haobo,Guo, Chenxi,Fu, Qiang,&Xiao, Jianping.(2019).Toward fundamentals of confined electrocatalysis in nanoscale reactors.Journal of physical chemistry letters,10(3),533-539. |
| MLA | Li, Haobo,et al."Toward fundamentals of confined electrocatalysis in nanoscale reactors".Journal of physical chemistry letters 10.3(2019):533-539. |
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来源：大连化学物理研究所
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