Highly effective transformation of carbohydrates to 5-hydroxymethylfurfural with al- montmorillonite as catalystr
文献类型：期刊论文
| 作者 | Cao, Jingjie1; Ma, Mingwei1; Liu, Jinchan1; Yang, Yongquan1; Liu, Hui1; Xu, Xingliang2; Huang, Jiahui3; Yue, Huijuan1; Tian, Ge1; Feng, Shouhua1 |
| 刊名 | Applied catalysis a-general
 |
| 出版日期 | 2019-02-05 |
| 卷号 | 571页码:96-101 |
| 关键词 | Biomass Energy Carbohydrates 5-hydroxymethylfurfural Catalysis |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2018.12.011 |
| 通讯作者 | Tian, ge(tiange@jlu.edu.cn) |
| 英文摘要 | Aluminum ion-exchanged ca-montmorillonite with different concentrations of aluminum ion were prepared and applied in the conversion of carbohydrates to 5-hydroxymethylfurfural (hmf). it was found that two types of acid sites were present in the catalyst, lewis acid sites for isomerization of glucose and bronsted acid sites for dehydration of fructose. with al-mont-10 as catalyst, the yield of hmf converted from glucose was 80.4% in a biphase system (thf: nacl solution) at 180 degrees c for 2.5 h. further, the catalyst also shows excellent catalytic performance in the conversion of starch and inulin, and the yield of hmf reached 60.1% and 81.6% under identical conditions, respectively. |
| WOS关键词 | GLUCOSE CONVERSION ; BETA ZEOLITE ; SN-BETA ; ACID ; DEHYDRATION ; FRUCTOSE ; BIOMASS ; LEWIS ; CLAY ; WATER |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| WOS类目 | Chemistry, Physical ; Environmental Sciences |
| 语种 | 英语 |
| WOS记录号 | WOS:000457661200010 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372801 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Tian, Ge |
| 作者单位 | 1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun, Jilin, Peoples R China 2.Shandong Agr Univ, Coll Chem & Mat Sci, Tai An, Shandong, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao, Jingjie,Ma, Mingwei,Liu, Jinchan,et al. Highly effective transformation of carbohydrates to 5-hydroxymethylfurfural with al- montmorillonite as catalystr[J]. Applied catalysis a-general,2019,571:96-101. |
| APA | Cao, Jingjie.,Ma, Mingwei.,Liu, Jinchan.,Yang, Yongquan.,Liu, Hui.,...&Feng, Shouhua.(2019).Highly effective transformation of carbohydrates to 5-hydroxymethylfurfural with al- montmorillonite as catalystr.Applied catalysis a-general,571,96-101. |
| MLA | Cao, Jingjie,et al."Highly effective transformation of carbohydrates to 5-hydroxymethylfurfural with al- montmorillonite as catalystr".Applied catalysis a-general 571(2019):96-101. |
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来源：大连化学物理研究所
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