Synthesis of acetyl-substituted tetrahydrobenzofuran and tetrahydronaphthalene via cascade diels-alder cycloadditions and dehydration of renewable furanics
文献类型：期刊论文
| 作者 | Marri, Mahender Reddy; Zhang, Xiaoqiang; Yan, Peifang; Ramineni, Kishore; Xia, Zhi; Huang, Tingyu; Balaga, Ravi; Zhang, Zongchao Conrad |
| 刊名 | Applied catalysis a-general
 |
| 出版日期 | 2019-01-25 |
| 卷号 | 570页码:107-112 |
| 关键词 | Diels-alder reaction Dehydration Sn-beta Bioderived products Furanics |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2018.11.004 |
| 通讯作者 | Zhang, zongchao conrad(zczhang@yahoo.com) |
| 英文摘要 | A acetyl-substituted tetrahydrobenzofuran, 1-(4,5,6,7-tetrahydro-1-benzofuran-6-yl)ethenone (6-acbzof) and a acetyl-substituted tetrahydronaphthalene, 1-(1,2,3,4-tetrahydronaphthalen-2-yl)ethenone (2-actnaph) were conveniently synthesized from renewable furanics by cascade diels-alder and dehydration reactions. the diels-alder cycloaddition of 4-(2-furyl)-3-buten-2-one (4-fb) with ethylene followed by dehydration in presence of zeolites was studied. sn grafted beta zeolite exhibited high performance with 69% yield of 2-actnaph starting from 4-fb. in this reaction, 6-acbzof was produced as intermediate. further, it was found that this acetyl substituted tetrahydrobenzofuran could be formed in high yield, 86%, in the absence of catalyst. for the first time in the literature, we report the synthesis of a renewable acetyl-substituted tetrahydronaphthalene in high yield from biomass-derived 4-fb in a tandem approach. while a acetyl-substituted tetrahydrobenzofuran could be prepared without a catalyst, catalyst was essential for the successful synthesis of the acetyl-substituted tetrahydronaphthalene. |
| WOS关键词 | BIOMASS-DERIVED DIMETHYLFURAN ; TEREPHTHALIC ACID ; O-QUINODIMETHANE ; ETHYLENE ; AROMATIZATION ; DERIVATIVES ; GENERATION ; CONVERSION ; CATALYSIS ; 2,5-DIMETHYLFURAN |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| WOS类目 | Chemistry, Physical ; Environmental Sciences |
| 语种 | 英语 |
| WOS记录号 | WOS:000457661500011 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372805 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Zhang, Zongchao Conrad |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Marri, Mahender Reddy,Zhang, Xiaoqiang,Yan, Peifang,et al. Synthesis of acetyl-substituted tetrahydrobenzofuran and tetrahydronaphthalene via cascade diels-alder cycloadditions and dehydration of renewable furanics[J]. Applied catalysis a-general,2019,570:107-112. |
| APA | Marri, Mahender Reddy.,Zhang, Xiaoqiang.,Yan, Peifang.,Ramineni, Kishore.,Xia, Zhi.,...&Zhang, Zongchao Conrad.(2019).Synthesis of acetyl-substituted tetrahydrobenzofuran and tetrahydronaphthalene via cascade diels-alder cycloadditions and dehydration of renewable furanics.Applied catalysis a-general,570,107-112. |
| MLA | Marri, Mahender Reddy,et al."Synthesis of acetyl-substituted tetrahydrobenzofuran and tetrahydronaphthalene via cascade diels-alder cycloadditions and dehydration of renewable furanics".Applied catalysis a-general 570(2019):107-112. |
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来源：大连化学物理研究所
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