Synthesis of spiropyrrolidine oxindoles through rh(ii)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides
文献类型：期刊论文
| 作者 | Yi, Ruxia1,2; Qian, Leilei1,2; Wan, Boshun1 |
| 刊名 | Chinese journal of catalysis
 |
| 出版日期 | 2019-02-01 |
| 卷号 | 40期号:2页码:177-183 |
| 关键词 | Rhodium catalyst Vinyl azides Diazo compounds Spiropyrrolidine oxindoles Olefination [1+1+3] annulation |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/s1872-2067(18)63200-0 |
| 通讯作者 | Wan, boshun(bswan@dicp.ac.cn) |
| 英文摘要 | A simple and efficient process involving the rh(ii)-catalyzed [1+1+3] annulation of diazooxindoles and vinyl azides has been developed for the synthesis of spiropyrrolidine oxindoles with potential biological activity and significant synthetic applications. this process involves a novel rhodium-catalyzed olefination of diazo compounds, followed by annulation with vinyl azides. this method is compatible with a broad range of substrates and affords moderate to good yields under mild reaction conditions. (c) 2019, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS关键词 | MICHAEL ADDITION/CYCLIZATION ; ENANTIOSELECTIVE SYNTHESIS ; EFFICIENT SYNTHESIS ; INDOLE ALKALOIDS ; CONSTRUCTION ; CYCLOADDITION ; ISATIN ; KETIMINES ; CASCADE |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000457815900006 |
| 出版者 | SCIENCE PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372844 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Wan, Boshun |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yi, Ruxia,Qian, Leilei,Wan, Boshun. Synthesis of spiropyrrolidine oxindoles through rh(ii)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides[J]. Chinese journal of catalysis,2019,40(2):177-183. |
| APA | Yi, Ruxia,Qian, Leilei,&Wan, Boshun.(2019).Synthesis of spiropyrrolidine oxindoles through rh(ii)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides.Chinese journal of catalysis,40(2),177-183. |
| MLA | Yi, Ruxia,et al."Synthesis of spiropyrrolidine oxindoles through rh(ii)-catalyzed olefination/cyclization of diazooxindoles and vinyl azides".Chinese journal of catalysis 40.2(2019):177-183. |
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来源：大连化学物理研究所
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