Rhodium(iii)-catalyzed enantioselective coupling of indoles and 7-azabenzonorbornadienes by c-h activation/desymmetrization
文献类型：期刊论文
| 作者 | Yang, Xifa2; Zheng, Guangfan1; Li, Xingwei1,2 |
| 刊名 | Angewandte chemie-international edition
 |
| 出版日期 | 2019-01-02 |
| 卷号 | 58期号:1页码:322-326 |
| 关键词 | C-h activation Desymmetrization Heterocycles Rhodium Synthetic methods |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201811998 |
| 通讯作者 | Zheng, guangfan(zhenggf@snnu.edu.cn) ; Li, xingwei(lixw@snnu.edu.cn) |
| 英文摘要 | Chiral rhodium(iii) cyclopentadienyl catalysts ((cprhiii)-rh-x) play significant roles in asymmetric arene c-h activation. rh/ir-catalyzed couplings of arenes and strained rings have been well-studied, but they have been limited to racemic systems. reported in this work is the (cprhiii)-rh-x/agsbf6-catalyzed enantioselective desymmetrizative c-c coupling of n-pyrimidylindoles and 7-azabenzonorbornadienes with high efficiency and enantioselectivity. the role of agsbf6 has been established by mechanistic studies. agsbf6 enhances the catalytic activity by suppressing the c3-h activation of the indoles, activation which would otherwise lead to catalytically inactive species. |
| WOS关键词 | RING-OPENING REACTIONS ; CHIRAL CYCLOPENTADIENYL LIGANDS ; BOND-FORMING REACTIONS ; HETEROBICYCLIC ALKENES ; ACTIVATION ; ARENES ; CATALYSTS ; AZABENZONORBORNADIENES ; HYDROARYLATIONS ; COMPLEXES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000455818400051 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372852 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Zheng, Guangfan; Li, Xingwei |
| 作者单位 | 1.Shaanxi Normal Univ SNNU, Sch Chem & Chem Engn, MOE, Key Lab Appl Surface & Colloid Chem, Xian 710062, Shaanxi, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xifa,Zheng, Guangfan,Li, Xingwei. Rhodium(iii)-catalyzed enantioselective coupling of indoles and 7-azabenzonorbornadienes by c-h activation/desymmetrization[J]. Angewandte chemie-international edition,2019,58(1):322-326. |
| APA | Yang, Xifa,Zheng, Guangfan,&Li, Xingwei.(2019).Rhodium(iii)-catalyzed enantioselective coupling of indoles and 7-azabenzonorbornadienes by c-h activation/desymmetrization.Angewandte chemie-international edition,58(1),322-326. |
| MLA | Yang, Xifa,et al."Rhodium(iii)-catalyzed enantioselective coupling of indoles and 7-azabenzonorbornadienes by c-h activation/desymmetrization".Angewandte chemie-international edition 58.1(2019):322-326. |
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来源：大连化学物理研究所
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