Semi-rigid molecular-clip-based molecular crystal gearshift
文献类型：期刊论文
| 作者 | Wu, Jia-Rui1; Li, Bao2; Zhang, Jiang-Wei3,4; Yang, Ying-Wei1 |
| 刊名 | Acs applied materials & interfaces
 |
| 出版日期 | 2019-01-09 |
| 卷号 | 11期号:1页码:998-1003 |
| ISSN号 | 1944-8244 |
| 关键词 | Molecular clip Crystalline materials X-ray diffraction Host-guest chemistry Molecular crystal gearshift |
| DOI | 10.1021/acsami.8b20108 |
| 通讯作者 | Yang, ying-wei(ywyang@jlu.edu.cn) |
| 英文摘要 | A new version of molecular clip, with a semi-rigid symmetrical crab type architecture and flexible cavity size, has been successfully designed and synthesized via a one-pot friedel crafts alkylation reaction. the x-ray single crystal diffraction data provide a simple and intuitive explanation, not only for its well-preorganized and regulated conformation but also for its selective and tunable guest-binding capability. for the first time, the newly designed molecular clip was demonstrated to be not only a controllable variable-speed nonporous adsorption material in solution iodine capture, but also capable of on off switching in volatile iodine capture. the presented new concept of molecular crystal gearshift directly from the molecular clip crystals represents an important advance in the development of synthetic receptor chemistry, which will exert a significant influence on small-molecule crystallography. |
| WOS关键词 | CHEMISTRY ; COMPLEXATION ; RECEPTORS |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| WOS类目 | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000455561200106 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372865 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Yang, Ying-Wei |
| 作者单位 | 1.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Int Joint Res Lab Nanomicro Architecture Chem, Coll Chem, 2699 Qanjin St, Changchun 130012, Jilin, Peoples R China 2.Jilin Univ, Inst Theoret Chem, State Key Lab Supramol Struct & Mat, 2699 Qanjin St, Changchun 130012, Jilin, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Jia-Rui,Li, Bao,Zhang, Jiang-Wei,et al. Semi-rigid molecular-clip-based molecular crystal gearshift[J]. Acs applied materials & interfaces,2019,11(1):998-1003. |
| APA | Wu, Jia-Rui,Li, Bao,Zhang, Jiang-Wei,&Yang, Ying-Wei.(2019).Semi-rigid molecular-clip-based molecular crystal gearshift.Acs applied materials & interfaces,11(1),998-1003. |
| MLA | Wu, Jia-Rui,et al."Semi-rigid molecular-clip-based molecular crystal gearshift".Acs applied materials & interfaces 11.1(2019):998-1003. |
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来源：大连化学物理研究所
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