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The structure of hexaaluminate and application in high-temperature reaction

文献类型:期刊论文

作者Zhu, Yanyan1; Yue, Zongyang1; Bian, Wen1; Liu, Ruilin1; Ma, Xiaoxun1; Wang, Xiaodong2
刊名Progress in chemistry
出版日期2018-12-15
卷号30期号:12页码:1992-2002
ISSN号1005-281X
关键词Hexaaluminate Metal substitution High-temperature catalysts Oxygen carriers Catalytic combustion N2o decomposition Chemical looping Relationship between structure and reaction performance
DOI10.7536/pc180406
通讯作者Zhu, yanyan(yanyanzhu2006@126.com) ; Wang, xiaodong(xdwang@dicp.ac.cn)
英文摘要Hexaaluminate materials exhibit remarkable thermal stability due to their peculiar layered structure. the al3+ ions in the hexaaluminate lattice can be substituted by transition or noble metals, giving rise to redox centers for a variety of reactions. oxygen in the mirror plane of hexaaluminate is loosely packed, making it a preferential diffusion route of oxygen. all of these favor the application of hexaaluminate in high-temperature oxygen-involved reaction. in this review, the structure of hexaaluminate is firstly introduced. furthermore, the effect of structure type (magnetoplumbite and beta-al2o3) and metal substitution on the microstructure of hexaaluminate (especially metal chemical state) are crefully described. then we discuss recent advances of hexaaluminate in high-temperature oxygen-involved reactions, such as, catalytic combustion of ch4, process-gas n2o abatement, decomposition of n2o as a propellant, ch4 chemical looping combustion and reforming, with a special emphasis on the relationship between the microstucture and reaction performance. at last, a brief summary and an outlook are given.
WOS关键词ALUMINATE SINGLE-CRYSTALS ; CATALYTIC COMBUSTION ; BARIUM HEXAALUMINATE ; SYNTHESIS GAS ; SUBSTITUTED HEXAALUMINATE ; CRYSTALLOGRAPHIC SITES ; PARTIAL OXIDATION ; OXYGEN CARRIER ; BETA-ALUMINA ; METHANE
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者CHINESE ACAD SCIENCES
WOS记录号WOS:000456019900017
URI标识http://www.irgrid.ac.cn/handle/1471x/2372891
专题大连化学物理研究所
通讯作者Zhu, Yanyan; Wang, Xiaodong
作者单位1.Northwest Univ, Sch Chem Engn,Int Sci & Technol Cooperat Base MOS, Chem Engn Res Ctr,Collaborat Innovat Ctr Dev Ener, Minist Educ Adv Use Technol Shanbei Energy,Shaanx, Xian 710069, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Yanyan,Yue, Zongyang,Bian, Wen,et al. The structure of hexaaluminate and application in high-temperature reaction[J]. Progress in chemistry,2018,30(12):1992-2002.
APA Zhu, Yanyan,Yue, Zongyang,Bian, Wen,Liu, Ruilin,Ma, Xiaoxun,&Wang, Xiaodong.(2018).The structure of hexaaluminate and application in high-temperature reaction.Progress in chemistry,30(12),1992-2002.
MLA Zhu, Yanyan,et al."The structure of hexaaluminate and application in high-temperature reaction".Progress in chemistry 30.12(2018):1992-2002.

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来源:大连化学物理研究所

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