Unlock the compact structure of lignocellulosic biomass by mild ball milling for ethylene glycol production
文献类型：期刊论文
| 作者 | Pang, Jifeng1; Zheng, Mingyuan1; Li, Xinsheng1,2; Sebastian, Joby1; Jiang, Yu1; Zhao, Yu1; Wang, Aiqin1; Zhang, Tao1 |
| 刊名 | Acs sustainable chemistry & engineering
 |
| 出版日期 | 2019-01-07 |
| 卷号 | 7期号:1页码:679-687 |
| 关键词 | Lignocellulosic biomass Ethylene glycol Ball milling Pretreatment Catalytic conversion |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.8b04262 |
| 通讯作者 | Zheng, mingyuan(myzheng@dicp.ac.cn) ; Zhang, tao(taozhang@dicp.ac.cn) |
| 英文摘要 | Ball milling pretreatment was found to be an efficient method to promote the catalytic conversion of lignocellulosic biomass to ethylene glycol (eg). after 3-6 h ball milling of miscanthus at 450 rpm, the eg yield reached about 52%, which is comparable to the result of pure cellulose conversion. the reasons of the promotion effect were investigated by characterizing the structure of biomass and the reaction residuals with x-ray diffraction, scanning electron microscopy, particle size distribution analyzer, contact angle measurement, thermogravimetric analysis-differential scanning calorimetry, and fourier-transform infrared spectroscopy. the mild ball milling liberated (hemi)cellulose from the compact plant tissues without affecting the crystallinity of cellulose. it reduced the size of biomass to 30 mu m and improved the accessibility of (hemi)cellulose, leading to a hydrophilic surface and high energy state of biomass for catalytic conversion. during the catalytic conversion, the mass transfer between sugar intermediates and heterogeneous hydrogenation catalysts were improved. correspondingly, the self-reaction of sugar intermediates, and the reactions between sugar intermediates and lignin fractions were suppressed, resulting in the high eg yield. |
| WOS关键词 | WATER-SOLUBLE MATERIALS ; CATALYTIC CONVERSION ; SUGAR ALCOHOLS ; MICROCRYSTALLINE CELLULOSE ; COMPOSITIONAL ANALYSIS ; BIOETHANOL PRODUCTION ; ENZYMATIC-HYDROLYSIS ; BARLEY STRAW ; PRETREATMENT ; ACID |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| WOS类目 | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000455288800071 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372902 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Zheng, Mingyuan; Zhang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pang, Jifeng,Zheng, Mingyuan,Li, Xinsheng,et al. Unlock the compact structure of lignocellulosic biomass by mild ball milling for ethylene glycol production[J]. Acs sustainable chemistry & engineering,2019,7(1):679-687. |
| APA | Pang, Jifeng.,Zheng, Mingyuan.,Li, Xinsheng.,Sebastian, Joby.,Jiang, Yu.,...&Zhang, Tao.(2019).Unlock the compact structure of lignocellulosic biomass by mild ball milling for ethylene glycol production.Acs sustainable chemistry & engineering,7(1),679-687. |
| MLA | Pang, Jifeng,et al."Unlock the compact structure of lignocellulosic biomass by mild ball milling for ethylene glycol production".Acs sustainable chemistry & engineering 7.1(2019):679-687. |
入库方式： iSwitch采集
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。