Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates
文献类型：期刊论文
| 作者 | Ping, Yifan1; Chang, Taiwei1; Wang, Kang1; Huo, Jingfeng1; Wang, Jianbo1,2 |
| 刊名 | Chemical communications
 |
| 出版日期 | 2019-01-04 |
| 卷号 | 55期号:1页码:59-62 |
| ISSN号 | 1359-7345 |
| DOI | 10.1039/c8cc09024f |
| 通讯作者 | Wang, jianbo(wangjb@pku.edu.cn) |
| 英文摘要 | A palladium-catalyzed oxidative borylation reaction of conjugated enynones is developed. this reaction represents a new method for the synthesis of furyl-substituted alkenylboronates. the reaction works well with a series of conjugated enynones. boryl migratory insertion of the palladium carbene intermediate is proposed as the key step in these transformations. |
| WOS关键词 | ENE-YNE-KETONES ; C-C BOND ; CROSS-COUPLING REACTION ; METAL CARBENE ; REGIOSELECTIVE SYNTHESIS ; DIAZOCARBONYL COMPOUNDS ; N-TOSYLHYDRAZONES ; ORGANIC-SYNTHESIS ; TERMINAL ALKYNES ; ACTIVATION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000453549600006 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372905 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ping, Yifan,Chang, Taiwei,Wang, Kang,et al. Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates[J]. Chemical communications,2019,55(1):59-62. |
| APA | Ping, Yifan,Chang, Taiwei,Wang, Kang,Huo, Jingfeng,&Wang, Jianbo.(2019).Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates.Chemical communications,55(1),59-62. |
| MLA | Ping, Yifan,et al."Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates".Chemical communications 55.1(2019):59-62. |
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来源：大连化学物理研究所
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