Rapid detection of trace volatile organic compounds by electric driven cryo-trap movable mass spectrometer
文献类型：期刊论文
| 作者 | Han Xiao-Xiao1; Li Jin-Xu2; Jiang Ji-Chun2; Wu Chen-Xin2; Chen Ping2; Zhang Zhi-Ping1; Hou Ke-Yong2; Li Hai-Yang2 |
| 刊名 | Chinese journal of analytical chemistry
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 46期号:5页码:642-649 |
| 关键词 | Volatile organic compounds Cryo-trap enrichment Movable mass spectrometer Trace determination |
| ISSN号 | 0253-3820 |
| DOI | 10.11895/j.issn.0253-3820.171459 |
| 通讯作者 | Hou ke-yong(houky@dicp.ac.cn) ; Li hai-yang(hli@dicp.ac.cn) |
| 英文摘要 | An electric driven cryo-trap enrichment apparatus for the movable mass spectrometer was designed to realize rapid and automatic detection of trace volatile organic compounds (vocs) in the atmosphere. compared with traditional cryo-trap with refrigerant, the lowest temperature of cryocooler was down to -196 degrees c and it was easy to carry due to its small size, light weight and refrigerant-free. cryo-trap combined with time-of-flight mass spectrometer was used to analyze benzene, toluene and xylene, and the result showed that the signal strength of benzene, toluene and xylene, with the cryo-trap enrichment, was improved by 212-fold, 254-fold and 242-fold, and the recoveries reached 98%, 87% and 87%, respectively. the analytical time for single sample was only 14 min. the electric driven cryo-trap combined with on-line mass spectrometer was used to detect 39 kinds of vocs listed in to-14 method of epa and ambient air, and the sensitivity of the newly designed instrument was better than the threshold of national indoor vocs. the combination of electric driven cryo-trap and time-of-flight mass spectrometer could be used for rapid enrichment and monitoring of trace vocs in the atmosphere and indoor air, showing great potential in in-site measurement and real-time monitoring of volatile organic pollutants. |
| WOS关键词 | AIR-QUALITY ; GAS ; OZONE ; TOFMS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Analytical |
| 语种 | 英语 |
| WOS记录号 | WOS:000455901700001 |
| 出版者 | ELSEVIER SCIENCE INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372907 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Hou Ke-Yong; Li Hai-Yang |
| 作者单位 | 1.Xian Shiyou Univ, Coll Chem & Chem Engn, Xian 710065, Shaanxi, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han Xiao-Xiao,Li Jin-Xu,Jiang Ji-Chun,et al. Rapid detection of trace volatile organic compounds by electric driven cryo-trap movable mass spectrometer[J]. Chinese journal of analytical chemistry,2018,46(5):642-649. |
| APA | Han Xiao-Xiao.,Li Jin-Xu.,Jiang Ji-Chun.,Wu Chen-Xin.,Chen Ping.,...&Li Hai-Yang.(2018).Rapid detection of trace volatile organic compounds by electric driven cryo-trap movable mass spectrometer.Chinese journal of analytical chemistry,46(5),642-649. |
| MLA | Han Xiao-Xiao,et al."Rapid detection of trace volatile organic compounds by electric driven cryo-trap movable mass spectrometer".Chinese journal of analytical chemistry 46.5(2018):642-649. |
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来源：大连化学物理研究所
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