Highly efficient synthesis of au-130(sph-br)(50) nanocluster
文献类型:期刊论文
作者 | Ren Xiuqing1,2; Fu Xuemei2,3; Lin Xinzhang2,3; Liu Chao2; Huang Jiahui2; Yan Jinghui1 |
刊名 | Chemical research in chinese universities
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出版日期 | 2018-10-01 |
卷号 | 34期号:5页码:719-722 |
关键词 | Au-130 Gold nanocluster Thiolate ligand |
ISSN号 | 1005-9040 |
DOI | 10.1007/s40242-018-8027-z |
通讯作者 | Liu chao(chaoliu@dicp.ac.cn) ; Yan jinghui(yjh@cust.edu.cn) |
英文摘要 | We reported the synthesis of au-130(sph-br)(50)(br-ph-sh=4-bromothiophenol) nanocluster with high purity and high yield via "size focusing" and "ligand exchange" processes. the time of synthetic process was significantly reduced compared with previous synthetic routine. au-130(sph-br)(50) was determined by uv-vis absorption spectroscopy and matrix-assisted laser desorption ionization(maldi) mass spectroscopy. thermo-gravimetric analysis (tga) and size-exclusion chromatogram(sec) analyses confirmed the purity of au-130(sph-br)(50). the yield of gold nanoclusters was 20%(based on haucl4). |
WOS关键词 | NOBLE-METAL NANOCLUSTERS ; GOLD NANOCLUSTERS ; CRYSTAL-STRUCTURE ; PROTECTED AU-130 ; CLUSTERS ; SIZE ; NANOPARTICLES ; TRANSFORMATION ; NANOMOLECULES ; STABILITY |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000454623400005 |
出版者 | HIGHER EDUCATION PRESS |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372917 |
专题 | 大连化学物理研究所 |
通讯作者 | Liu Chao; Yan Jinghui |
作者单位 | 1.Changchun Univ Sci & Technol, Sch Chem & Environm Engn, Changchun 130022, Jilin, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Gold Catalysis Res Ctr, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ren Xiuqing,Fu Xuemei,Lin Xinzhang,et al. Highly efficient synthesis of au-130(sph-br)(50) nanocluster[J]. Chemical research in chinese universities,2018,34(5):719-722. |
APA | Ren Xiuqing,Fu Xuemei,Lin Xinzhang,Liu Chao,Huang Jiahui,&Yan Jinghui.(2018).Highly efficient synthesis of au-130(sph-br)(50) nanocluster.Chemical research in chinese universities,34(5),719-722. |
MLA | Ren Xiuqing,et al."Highly efficient synthesis of au-130(sph-br)(50) nanocluster".Chemical research in chinese universities 34.5(2018):719-722. |
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来源:大连化学物理研究所
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