中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Highly efficient synthesis of au-130(sph-br)(50) nanocluster

文献类型:期刊论文

作者Ren Xiuqing1,2; Fu Xuemei2,3; Lin Xinzhang2,3; Liu Chao2; Huang Jiahui2; Yan Jinghui1
刊名Chemical research in chinese universities
出版日期2018-10-01
卷号34期号:5页码:719-722
关键词Au-130 Gold nanocluster Thiolate ligand
ISSN号1005-9040
DOI10.1007/s40242-018-8027-z
通讯作者Liu chao(chaoliu@dicp.ac.cn) ; Yan jinghui(yjh@cust.edu.cn)
英文摘要We reported the synthesis of au-130(sph-br)(50)(br-ph-sh=4-bromothiophenol) nanocluster with high purity and high yield via "size focusing" and "ligand exchange" processes. the time of synthetic process was significantly reduced compared with previous synthetic routine. au-130(sph-br)(50) was determined by uv-vis absorption spectroscopy and matrix-assisted laser desorption ionization(maldi) mass spectroscopy. thermo-gravimetric analysis (tga) and size-exclusion chromatogram(sec) analyses confirmed the purity of au-130(sph-br)(50). the yield of gold nanoclusters was 20%(based on haucl4).
WOS关键词NOBLE-METAL NANOCLUSTERS ; GOLD NANOCLUSTERS ; CRYSTAL-STRUCTURE ; PROTECTED AU-130 ; CLUSTERS ; SIZE ; NANOPARTICLES ; TRANSFORMATION ; NANOMOLECULES ; STABILITY
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
WOS记录号WOS:000454623400005
出版者HIGHER EDUCATION PRESS
URI标识http://www.irgrid.ac.cn/handle/1471x/2372917
专题大连化学物理研究所
通讯作者Liu Chao; Yan Jinghui
作者单位1.Changchun Univ Sci & Technol, Sch Chem & Environm Engn, Changchun 130022, Jilin, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Gold Catalysis Res Ctr, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Ren Xiuqing,Fu Xuemei,Lin Xinzhang,et al. Highly efficient synthesis of au-130(sph-br)(50) nanocluster[J]. Chemical research in chinese universities,2018,34(5):719-722.
APA Ren Xiuqing,Fu Xuemei,Lin Xinzhang,Liu Chao,Huang Jiahui,&Yan Jinghui.(2018).Highly efficient synthesis of au-130(sph-br)(50) nanocluster.Chemical research in chinese universities,34(5),719-722.
MLA Ren Xiuqing,et al."Highly efficient synthesis of au-130(sph-br)(50) nanocluster".Chemical research in chinese universities 34.5(2018):719-722.

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来源:大连化学物理研究所

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