Synthesis, characterization and luminescent properties of two copper(i) complexes based on 2,2 '-biquinoline and phosphorous ligand
文献类型：期刊论文
| 作者 | Sun Ling-Zhi1; Wang Yu1; Lin Sen1; Liu Jian-Ming2; Li Zhong-Feng1; Zhang Jiang-Wei3; Jin Qiong-Hua1 |
| 刊名 | Chinese journal of structural chemistry
 |
| 出版日期 | 2018-08-15 |
| 卷号 | 37期号:8页码:1313-1322 |
| 关键词 | Copper Crystal structures 2,2 '-biquinoline Luminescence |
| ISSN号 | 0254-5861 |
| DOI | 10.14102/j.cnki.0254-5861.2011-1942 |
| 通讯作者 | Jin qiong-hua(jinqh@cnu.edu.cn) |
| 英文摘要 | Three new copper(i) complexes, namely [cu(dpephos)(biq)]cf3so3 (1) and [cu(pph3)(2)(biq)]cf3so3 (2) and [cu(pph3)(2)(biq)]clo4(3) (dpephos = bis [2-(diphenylphosp hino)phenyl]ether, pph3 = triphenylphosphine and biq = 2,2'-biquinoline), are synthesized and characterized by ir, h-1 nmr, p-31 nmr, fluorescence spectra and terahertz time-domain spectroscopy (thz-tds). complex 1 crystallizes in triclinic, space group p (1) over bar with a = 12.6997(5), b = 13.2813(5), c = 15.3593(6) angstrom, alpha = 80.211(3)degrees, beta= 88.752(3)degrees, gamma = 70.113(3)degrees, v = 2398.85(15) angstrom(3), c55h41.2cuf3n2o2,m-r = 1018.27, z = 2, d-c = 1.410 g/cm(3), f(000) = 1048, mu = 0.628 mm(-1), the final r = 0.0450 and wr = 0.1105 for 9419 observed reflections (i > 2 sigma(i)). complex 2 crystallizes in monoclinic, space group c2/c with a = 19.9961(7), b = 15.9774(5), c = 17.7908(6) angstrom, beta = 119.758(4)degrees, v = 4982.8(3) angstrom(3), c56.47h47.88cuf3n2o4.47p2s, mr = 1040.54, z = 4, d-c = 1.387 g/cm(3), f(000) = 2154, mu = 0.606 mm(-1), the final r = 0.0430 and wr = 0.1218 for 4897 observed reflections (i > 2 sigma(i)). complex 3 crystallizes in monoclinic, space group c2/c with a = 19.7534(8), b = 15.0797(5), c = 17.8097(7) angstrom, beta = 116.400(5)degrees, v = 4751.8(3) angstrom(3), c-56 h(45)c1cun(3)o(4)p(2), m-r= 984.88, z = 4, d-c= 1.377 g/cm(3), f(000) = 2040, mu = 0.635 mm(-1), the final r = 0.0731 and wr = 0.2180 for 4670 observed reflections (i > 2 sigma(i)). in the emission spectra, shifts of emission peak are derived from ligand-centered (pi-pi*) transition. |
| WOS关键词 | STRUCTURAL-CHARACTERIZATION ; SILVER(I) COMPLEXES ; SERIES ; ANION |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000454083000015 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372932 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Jin Qiong-Hua |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China 2.Peking Univ, Sch Math Sci, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Gold Catalysis Res Ctr, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun Ling-Zhi,Wang Yu,Lin Sen,et al. Synthesis, characterization and luminescent properties of two copper(i) complexes based on 2,2 '-biquinoline and phosphorous ligand[J]. Chinese journal of structural chemistry,2018,37(8):1313-1322. |
| APA | Sun Ling-Zhi.,Wang Yu.,Lin Sen.,Liu Jian-Ming.,Li Zhong-Feng.,...&Jin Qiong-Hua.(2018).Synthesis, characterization and luminescent properties of two copper(i) complexes based on 2,2 '-biquinoline and phosphorous ligand.Chinese journal of structural chemistry,37(8),1313-1322. |
| MLA | Sun Ling-Zhi,et al."Synthesis, characterization and luminescent properties of two copper(i) complexes based on 2,2 '-biquinoline and phosphorous ligand".Chinese journal of structural chemistry 37.8(2018):1313-1322. |
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来源：大连化学物理研究所
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