Quasi-amorphous metallic nickel nanopowder as an efficient and durable electrocatalyst for alkaline hydrogen evolution
文献类型：期刊论文
| 作者 | Zhang, Doudou1,2; Shi, Jingying2; Qi, Yu2; Wang, Xiaomei2; Wang, Hong2; Li, Mingrun2; Liu, Shengzhong1,2; Li, Can2 |
| 刊名 | Advanced science
 |
| 出版日期 | 2018-12-01 |
| 卷号 | 5期号:12页码:7 |
| 关键词 | Alkaline solutions Chemical synthesis Electrocatalysts Hydrogen evolution reaction Quasi-amorphous metallic nickel |
| ISSN号 | 2198-3844 |
| DOI | 10.1002/advs.201801216 |
| 通讯作者 | Shi, jingying(jingyingshi@dicp.ac.cn) ; Liu, shengzhong(szliu@dicp.ac.cn) |
| 英文摘要 | Nickel is regarded as the best alternative metal electrocatalyst to platinum for hydrogen evolution reaction (her). success in developing a quasi-amorphous metallic nickel (qamn) nanopowder catalyst using a two-step chemical route for efficient and durable her in alkaline solution is reported. it is found that the qamn electrocatalyst exhibits essentially zero overpotential at the cathodic onset while delivering 10 ma cm(-2) at an overpotential of only 240 mv; both performances are far better than what was reported previously using prior metallic nickel catalysts. taking into account increased surface area, further enhanced activity is attributed to the superior intrinsic activity. meanwhile, the qamn catalyst shows excellent stability in accelerated and interrupted polarization in alkaline solution for tens of hours. this study provides a new chemical means to prepare amorphous metallic materials for more efficient catalysis. |
| WOS关键词 | OXYGEN EVOLUTION ; SULFIDE CATALYST ; HIGHLY EFFICIENT ; WATER ; NANOPARTICLES ; REDUCTION ; TUNGSTEN ; GENERATION ; PHOSPHIDE ; GRAPHENE |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| WOS类目 | Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000453685900020 |
| 出版者 | WILEY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372958 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Shi, Jingying; Liu, Shengzhong |
| 作者单位 | 1.Shaanxi Normal Univ, Sch Mat Sci & Engn,Key Lab Appl Surface & Colloid, Shaanxi Engn Lab Adv Energy Technol,Minist Educ, Shaanxi Key Lab Adv Energy Devices,Inst Adv Energ, Xian 710119, Shaanxi, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy IChEM, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Doudou,Shi, Jingying,Qi, Yu,et al. Quasi-amorphous metallic nickel nanopowder as an efficient and durable electrocatalyst for alkaline hydrogen evolution[J]. Advanced science,2018,5(12):7. |
| APA | Zhang, Doudou.,Shi, Jingying.,Qi, Yu.,Wang, Xiaomei.,Wang, Hong.,...&Li, Can.(2018).Quasi-amorphous metallic nickel nanopowder as an efficient and durable electrocatalyst for alkaline hydrogen evolution.Advanced science,5(12),7. |
| MLA | Zhang, Doudou,et al."Quasi-amorphous metallic nickel nanopowder as an efficient and durable electrocatalyst for alkaline hydrogen evolution".Advanced science 5.12(2018):7. |
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来源：大连化学物理研究所
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