Single-atom catalyst: a rising star for green synthesis of fine chemicals
文献类型：期刊论文
| 作者 | Zhang, Leilei1; Ren, Yujing1,2; Liu, Wengang1,2; Wang, Aiqin1; Zhang, Tao1 |
| 刊名 | National science review
 |
| 出版日期 | 2018-09-01 |
| 卷号 | 5期号:5页码:653-672 |
| 关键词 | Single-atom catalysts Fine chemicals Green synthesis Structure-reactivity relationship Heterogeneous catalysis |
| ISSN号 | 2095-5138 |
| DOI | 10.1093/nsr/nwy077 |
| 通讯作者 | Wang, aiqin(aqwang@dicp.ac.cn) ; Zhang, tao(taozhang@dicp.ac.cn) |
| 英文摘要 | The green synthesis of fine chemicals calls for a new generation of efficient and robust catalysts. single-atom catalysts (sacs), in which all metal species are atomically dispersed on a solid support, and which often consist of well-defined mononuclear active sites, are expected to bridge homogeneous and heterogeneous catalysts for liquid-phase organic transformations. this review summarizes major advances in the sac-catalysed green synthesis of fine chemicals in the past several years, with a focus on the catalytic activity, selectivity and reusability of sacs in various organic reactions. the relationship between catalytic performance and the active site structure is discussed in terms of the valence state, coordination environment and anchoring chemistry of single atoms to the support, in an effort to guide the rational design of sacs in this special area, which has traditionally been dominated by homogeneous catalysis. finally, the challenges remaining in this research area are discussed and possible future research directions are proposed. |
| WOS关键词 | N-C CATALYST ; SELECTIVE AEROBIC OXIDATION ; FIXED-BED HYDROFORMYLATION ; FRUSTRATED LEWIS PAIRS ; CHEMOSELECTIVE HYDROGENATION ; FUNCTIONALIZED NITROARENES ; LEVULINIC ACID ; ETHYLENE-GLYCOL ; EFFICIENT ; REDUCTION |
| WOS研究方向 | Science & Technology - Other Topics |
| WOS类目 | Multidisciplinary Sciences |
| 语种 | 英语 |
| WOS记录号 | WOS:000448667000016 |
| 出版者 | OXFORD UNIV PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372972 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Wang, Aiqin; Zhang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Leilei,Ren, Yujing,Liu, Wengang,et al. Single-atom catalyst: a rising star for green synthesis of fine chemicals[J]. National science review,2018,5(5):653-672. |
| APA | Zhang, Leilei,Ren, Yujing,Liu, Wengang,Wang, Aiqin,&Zhang, Tao.(2018).Single-atom catalyst: a rising star for green synthesis of fine chemicals.National science review,5(5),653-672. |
| MLA | Zhang, Leilei,et al."Single-atom catalyst: a rising star for green synthesis of fine chemicals".National science review 5.5(2018):653-672. |
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来源：大连化学物理研究所
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