Isolation and characterization of four phosphorus cluster anions p-7(3-), p-14(4-), p-16(2-) and p-26(4-) from the nucleophilic functionalization of white phosphorus with 1,4-dilithio-1,3-butadienes
文献类型：期刊论文
| 作者 | Du, Shanshan; Hu, Jingyuan; Chai, Zhengqi; Zhang, Wen-Xiong; Xi, Zhenfeng |
| 刊名 | Chinese journal of chemistry
 |
| 出版日期 | 2019 |
| 卷号 | 37期号:1页码:71-75 |
| ISSN号 | 1001-604X |
| 关键词 | Organolithium Phosphorus clusters P4 functionalization Phospholyl lithium White phosphorus |
| DOI | 10.1002/cjoc.201800482 |
| 通讯作者 | Zhang, wen-xiong(wx_zhang@pku.edu.cn) |
| 英文摘要 | .summary of main observation and conclusion studies on the aggregation degrees of negatively charged phosphides derived from the nucleophilic p-4 functionalization could help understand the pathway of phosphorus atoms degradation or aggregation. in this report, we have isolated and characterized four phosphorus cluster anions (p-7(3-), p-14(4-), p-16(2-), and p-26(4-)) from the nucleophilic functionalization of p-4 with 1,4-dilithio-1,3-butadienes. these phosphorus clusters could be rationalized as the p-atom-containing products besides the main phospholyl lithium. their structural features and p-31 nmr behaviors are discussed based on single crystal x-ray diffraction analysis and p-31{h-1} cosy nmr analysis. |
| WOS关键词 | P-4 ACTIVATION ; ELEMENTAL PHOSPHORUS ; CRYSTAL-STRUCTURES ; REACTIVITY ; CHEMISTRY ; POLYPHOSPHIDES ; COMPLEX ; BOND ; PHOSPHIDES ; LIGAND |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000453403000012 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372973 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Zhang, Wen-Xiong |
| 作者单位 | Peking Univ, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Minist Educ,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Shanshan,Hu, Jingyuan,Chai, Zhengqi,et al. Isolation and characterization of four phosphorus cluster anions p-7(3-), p-14(4-), p-16(2-) and p-26(4-) from the nucleophilic functionalization of white phosphorus with 1,4-dilithio-1,3-butadienes[J]. Chinese journal of chemistry,2019,37(1):71-75. |
| APA | Du, Shanshan,Hu, Jingyuan,Chai, Zhengqi,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2019).Isolation and characterization of four phosphorus cluster anions p-7(3-), p-14(4-), p-16(2-) and p-26(4-) from the nucleophilic functionalization of white phosphorus with 1,4-dilithio-1,3-butadienes.Chinese journal of chemistry,37(1),71-75. |
| MLA | Du, Shanshan,et al."Isolation and characterization of four phosphorus cluster anions p-7(3-), p-14(4-), p-16(2-) and p-26(4-) from the nucleophilic functionalization of white phosphorus with 1,4-dilithio-1,3-butadienes".Chinese journal of chemistry 37.1(2019):71-75. |
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来源：大连化学物理研究所
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