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Bandgap engineering of dual acceptor-containing naphthalene diimide polymers for all-polymer solar cells

文献类型:期刊论文

作者Tu, Dandan1,2; Liu, Xuan1,2; Zhang, Jing1,2; Yang, Qing1,2; Yu, Shuwen1,3; Guo, Xin1,3; Li, Can1,3
刊名Acs sustainable chemistry & engineering
出版日期2018-12-01
卷号6期号:12页码:16005-16010
ISSN号2168-0485
关键词Naphthalene diimide polymers All-polymer solar cells Complementary absorption Dual-acceptor strategy
DOI10.1021/acssuschemeng.8b05021
通讯作者Guo, xin(guoxin@dicp.ac.cn) ; Li, can(canli@dicp.ac.cn)
英文摘要Naphthalene diimide (ndi)-based polymers, as nonfullerene acceptors for all-polymer solar cells (all-pscs), are usually investigated by manipulating electron donating units, which have a narrow bandgap showing absorption spectra mostly overlapping with high-performance donor polymers like ptb7-th. in order to gain complementary absorptions between ndi-based polymers and ptb7-th, we report three ndi-based polymers (p1-p3) designed by a dual-acceptor strategy and systematically study their effect on the bandgap, molecular configuration, and charge transport property. the absorption bands of these polymers range from 300 to 800 nm; in particular, p1 with a maximum absorption at 530 nm exhibits a good complementary absorption with the ptb7-th. the device based on the ptb7-th:p1 blend provides higher j(sc) and efficiency than those based on other two polymers. the result suggests that the dual-acceptor strategy is effective to design acceptor polymers with adjustable absorption and molecular configuration for the all-pscs.
WOS关键词POWER CONVERSION EFFICIENCY ; OPTIMIZATION ; COPOLYMERS ; SOLVENT ; DONOR
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Engineering
WOS类目Chemistry, Multidisciplinary ; GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY ; Engineering, Chemical
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000452344900013
URI标识http://www.irgrid.ac.cn/handle/1471x/2372994
专题大连化学物理研究所
通讯作者Guo, Xin; Li, Can
作者单位1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Zhongshan Rd 457, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Tu, Dandan,Liu, Xuan,Zhang, Jing,et al. Bandgap engineering of dual acceptor-containing naphthalene diimide polymers for all-polymer solar cells[J]. Acs sustainable chemistry & engineering,2018,6(12):16005-16010.
APA Tu, Dandan.,Liu, Xuan.,Zhang, Jing.,Yang, Qing.,Yu, Shuwen.,...&Li, Can.(2018).Bandgap engineering of dual acceptor-containing naphthalene diimide polymers for all-polymer solar cells.Acs sustainable chemistry & engineering,6(12),16005-16010.
MLA Tu, Dandan,et al."Bandgap engineering of dual acceptor-containing naphthalene diimide polymers for all-polymer solar cells".Acs sustainable chemistry & engineering 6.12(2018):16005-16010.

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来源:大连化学物理研究所

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