Transition metal-nitrogen sites for electrochemical carbon dioxide reduction reaction
文献类型：期刊论文
| 作者 | Yan, Chengcheng1,2; Lin, Long1,2; Wang, Guoxiong1,3; Bao, Xinhe1,3 |
| 刊名 | Chinese journal of catalysis
 |
| 出版日期 | 2019 |
| 卷号 | 40期号:1页码:23-37 |
| 关键词 | Electrochemical carbon dioxide reduction reaction Metal-nitrogen sites Metal-nitrogen containing macrocyclic complexes Metal organic frameworks Zeolitic imidazolate frameworks Carbon material doped with metal-nitrogen sites |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/s1872-2067(18)63161-4 |
| 通讯作者 | Wang, guoxiong(wanggx@dicp.ac.cn) ; Bao, xinhe(xhbao@dicp.ac.cn) |
| 英文摘要 | Electrochemical co2 reduction reaction (co2rr) powered by renewable electricity has emerged as the most promising technique for co2 conversion, making it possible to realize a carbon-neutral cycle. highly efficient, robust, and cost-effective catalysts are highly demanded for the near-future practical applications of co2rr. previous studies on atomically dispersed metal-nitrogen (m-n-x) sites constituted of earth abundant elements with maximum atom-utilization efficiency have demonstrated their performance towards co2rr. this review summarizes recent advances on a variety of m-n-x sites-containing transition metal-centered macrocyclic complexes, metal organic frameworks, and m-n-x-doped carbon materials for efficient co2rr, including both experimental and theoretical studies. the roles of metal centers, coordinated ligands, and conductive supports on the intrinsic activity and selectivity, together with the importance of reaction conditions for improved performance are discussed. the mechanisms of co2rr over these m-n-x-containing materials are presented to provide useful guidance for the rational design of efficient catalysts towards co2rr. (c) 2019, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS关键词 | GAS-DIFFUSION ELECTRODES ; OXYGEN REDUCTION ; ORGANIC FRAMEWORKS ; CO2 REDUCTION ; ELECTROCATALYTIC REDUCTION ; HIGHLY EFFICIENT ; COBALT-PORPHYRIN ; HETEROGENEOUS CATALYSTS ; POROUS CARBON ; ELECTROREDUCTION |
| WOS研究方向 | Chemistry ; Engineering |
| WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
| 语种 | 英语 |
| WOS记录号 | WOS:000453646500004 |
| 出版者 | SCIENCE PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2372999 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Wang, Guoxiong; Bao, Xinhe |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Ctr Excellence Nanosci, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan, Chengcheng,Lin, Long,Wang, Guoxiong,et al. Transition metal-nitrogen sites for electrochemical carbon dioxide reduction reaction[J]. Chinese journal of catalysis,2019,40(1):23-37. |
| APA | Yan, Chengcheng,Lin, Long,Wang, Guoxiong,&Bao, Xinhe.(2019).Transition metal-nitrogen sites for electrochemical carbon dioxide reduction reaction.Chinese journal of catalysis,40(1),23-37. |
| MLA | Yan, Chengcheng,et al."Transition metal-nitrogen sites for electrochemical carbon dioxide reduction reaction".Chinese journal of catalysis 40.1(2019):23-37. |
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来源：大连化学物理研究所
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