Enantiodivergent desymmetrization in the rhodium( iii)-catalyzed annulation of sulfoximines with diazo compounds
文献类型：期刊论文
| 作者 | Shen, Bingxue1,2; Wan, Boshun1; Li, Xingwei1,3 |
| 刊名 | Angewandte chemie-international edition
 |
| 出版日期 | 2018-11-19 |
| 卷号 | 57期号:47页码:15534-15538 |
| 关键词 | Asymmetric c-h activation Desymmetrization Enantiodivergence Rhodium Sulfoximes |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201810472 |
| 通讯作者 | Li, xingwei(xwli@dicp.ac.cn) |
| 英文摘要 | Rh-iii- and ir-iii-catalyzed asymmetric c-h functionalization reactions of arenes have relied on the employment of chiral rh-iii/ir-iii cyclopentadienyl catalysts, the introduction of chiral carboxylic acids to achiral cp*rhx2 catalysts, and the integration of both strategies. despite considerable progress, each reaction only provided a specific configuration of the enantioenriched product when using a particular chiral catalyst. reported in this work is the enantiodivergent coupling of sulfoximines with various diazo compounds by rh-iii-catalyzed desymmetrizing annulation. the enantiodivergence was enabled by a judicious choice of achiral carboxylic acids, and the enantioselectivity correlates with the steric bias of the carboxylic acid and the sulfoximine. |
| WOS关键词 | C-H ACTIVATION ; N BOND ; ASYMMETRIC-SYNTHESIS ; 2+2+2 CYCLOADDITION ; FUNCTIONALIZATION ; LIGANDS ; COMBINATION ; CATALYSIS ; RH |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000453344500041 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373009 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Shaanxi Normal Univ SNNU, Sch Chem & Chem Engn, Xian 710062, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Bingxue,Wan, Boshun,Li, Xingwei. Enantiodivergent desymmetrization in the rhodium( iii)-catalyzed annulation of sulfoximines with diazo compounds[J]. Angewandte chemie-international edition,2018,57(47):15534-15538. |
| APA | Shen, Bingxue,Wan, Boshun,&Li, Xingwei.(2018).Enantiodivergent desymmetrization in the rhodium( iii)-catalyzed annulation of sulfoximines with diazo compounds.Angewandte chemie-international edition,57(47),15534-15538. |
| MLA | Shen, Bingxue,et al."Enantiodivergent desymmetrization in the rhodium( iii)-catalyzed annulation of sulfoximines with diazo compounds".Angewandte chemie-international edition 57.47(2018):15534-15538. |
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来源：大连化学物理研究所
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