Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates via c-h bond activation
文献类型：期刊论文
| 作者 | Tian, Miaomiao1; Yang, Xifa2; Zhang, Bo1; Liu, Bingxian1; Li, Xingwei1,2,3 |
| 刊名 | Organic chemistry frontiers
 |
| 出版日期 | 2018-12-07 |
| 卷号 | 5期号:23页码:3406-3409 |
| ISSN号 | 2052-4129 |
| DOI | 10.1039/c8qo00947c |
| 通讯作者 | Li, xingwei(xwli@dicp.ac.cn) |
| 英文摘要 | Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates has been realized. this reaction proceeded via chelation-assisted c-h activation, olefin insertion and -f elimination, leading to the synthesis of monofluoroalkenes with high z-selectivity with respect to the olefin. this catalytic system is highly efficient over a broad range of substrates under mild and redox-neutral conditions. |
| WOS关键词 | ALPHA-FLUOROALKENYLATION ; FLUORINE ; ARENES ; CATALYSIS ; NITROSO ; FUNCTIONALIZATIONS ; PHARMACEUTICALS ; INDOLES ; MIMICS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000450737800007 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373031 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | 1.Henan Normal Univ, Sch Chem & Chem Engn, Henan Key Lab Organ Funct Mol & Drug Innovat, Xinxiang 453007, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710119, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian, Miaomiao,Yang, Xifa,Zhang, Bo,et al. Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates via c-h bond activation[J]. Organic chemistry frontiers,2018,5(23):3406-3409. |
| APA | Tian, Miaomiao,Yang, Xifa,Zhang, Bo,Liu, Bingxian,&Li, Xingwei.(2018).Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates via c-h bond activation.Organic chemistry frontiers,5(23),3406-3409. |
| MLA | Tian, Miaomiao,et al."Rh(iii)-catalyzed -fluoroalkenylation of n-nitrosoanilines with 2,2-difluorovinyl tosylates via c-h bond activation".Organic chemistry frontiers 5.23(2018):3406-3409. |
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来源：大连化学物理研究所
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