Facile construction of hydrogenated azepino[3,2,1-hi]indoles by rh(iii)-catalyzed c-h activation/[5+2] annulation of n-cyanoacetylindolines with sulfoxonium ylides
文献类型：期刊论文
| 作者 | Hu, Panjie1; Zhang, Ying1; Liu, Bingxian1; Li, Xingwei1,2 |
| 刊名 | Organic chemistry frontiers
 |
| 出版日期 | 2018-11-21 |
| 卷号 | 5期号:22页码:3263-3266 |
| ISSN号 | 2052-4129 |
| DOI | 10.1039/c8qo00861b |
| 通讯作者 | Liu, bingxian(liubx1120@163.com) ; Li, xingwei(xwli@dicp.ac.cn) |
| 英文摘要 | Rhodium(iii)-catalyzed regio- and chemoselective [5 + 2] annulation between n-(cyanoacetyl)indolines and sulfoxonium ylides has been realized, leading to efficient construction of seven-membered rings under mild conditions. this reaction proceeded via c-h activation with sulfoxonium ylides as carbene synthons. |
| WOS关键词 | CASCADE OXIDATIVE ANNULATION ; ALPHA,BETA-UNSATURATED ALDEHYDES ; BOND FUNCTIONALIZATION ; INTERNAL ALKYNES ; ACTIVATION ; ARENES ; DERIVATIVES ; CYCLIZATION ; CLEAVAGE ; KETONES |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000449412800010 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373088 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Liu, Bingxian; Li, Xingwei |
| 作者单位 | 1.Henan Normal Univ, Henan Key Lab Organ Funct Mol & Drug Innovat, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Panjie,Zhang, Ying,Liu, Bingxian,et al. Facile construction of hydrogenated azepino[3,2,1-hi]indoles by rh(iii)-catalyzed c-h activation/[5+2] annulation of n-cyanoacetylindolines with sulfoxonium ylides[J]. Organic chemistry frontiers,2018,5(22):3263-3266. |
| APA | Hu, Panjie,Zhang, Ying,Liu, Bingxian,&Li, Xingwei.(2018).Facile construction of hydrogenated azepino[3,2,1-hi]indoles by rh(iii)-catalyzed c-h activation/[5+2] annulation of n-cyanoacetylindolines with sulfoxonium ylides.Organic chemistry frontiers,5(22),3263-3266. |
| MLA | Hu, Panjie,et al."Facile construction of hydrogenated azepino[3,2,1-hi]indoles by rh(iii)-catalyzed c-h activation/[5+2] annulation of n-cyanoacetylindolines with sulfoxonium ylides".Organic chemistry frontiers 5.22(2018):3263-3266. |
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来源：大连化学物理研究所
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