Polyoxometalate catalysts with co-substituted vo2+ and transition metals and their catalytic performance for the oxidation of isobutane
文献类型：期刊论文
| 作者 | Liu, Yanchun1; He, Jingfang1,2; Chu, Wenling1; Yang, Weishen1 |
| 刊名 | Catalysis science & technology
 |
| 出版日期 | 2018-11-21 |
| 卷号 | 8期号:22页码:5774-5781 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c8cy01101j |
| 通讯作者 | Chu, wenling(cwl@dicp.ac.cn) ; Yang, weishen(yangws@dicp.ac.cn) |
| 英文摘要 | Cs-salts of the keggin-type phosphomolybdic acid with simultaneous doping of vo2+ and different transition metals are prepared, characterized and tested as catalysts for the oxidation of isobutane to methacrylic acid under isobutane-rich conditions. the results show that cs2.0v0.3cu0.2pmo12o40 catalyst with co-substituted vo2+ and cu2+ in its secondary structure exhibits higher catalytic performance than those with co-doped vo2+ and other transition metals such as fe, ni and ce. this difference is ascribed to the synergistic effect between cu2+ and vo2+ only in the secondary structure. this synergistic effect is related to the charge transfer between mo6+ in the keggin anions and cu2+ counter cation, which promotes the re-oxidation of the catalyst and consequently its catalytic activity. |
| WOS关键词 | ONE-STEP SYNTHESIS ; SELECTIVE OXIDATION ; KEGGIN-TYPE ; METHACRYLIC-ACID ; HETEROPOLY COMPOUNDS ; 12-MOLYBDOPHOSPHORIC ACID ; PHOSPHOMOLYBDIC ACID ; METHACROLEIN ; CESIUM ; VANADIUM |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000450091300004 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373091 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Chu, Wenling; Yang, Weishen |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yanchun,He, Jingfang,Chu, Wenling,et al. Polyoxometalate catalysts with co-substituted vo2+ and transition metals and their catalytic performance for the oxidation of isobutane[J]. Catalysis science & technology,2018,8(22):5774-5781. |
| APA | Liu, Yanchun,He, Jingfang,Chu, Wenling,&Yang, Weishen.(2018).Polyoxometalate catalysts with co-substituted vo2+ and transition metals and their catalytic performance for the oxidation of isobutane.Catalysis science & technology,8(22),5774-5781. |
| MLA | Liu, Yanchun,et al."Polyoxometalate catalysts with co-substituted vo2+ and transition metals and their catalytic performance for the oxidation of isobutane".Catalysis science & technology 8.22(2018):5774-5781. |
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来源：大连化学物理研究所
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