Diphosphine-induced chiral propeller arrangement of gold nanoclusters for singlet oxygen photogeneration
文献类型：期刊论文
| 作者 | Zhang, Jiangwei1; Zhou, Yang1,2; Zheng, Kai1; Abroshan, Hadi3; Kauffman, Douglas R.4; Sun, Junliang5; Li, Gao1 |
| 刊名 | Nano research
 |
| 出版日期 | 2018-11-01 |
| 卷号 | 11期号:11页码:5787-5798 |
| ISSN号 | 1998-0124 |
| 关键词 | Gold nanoclusters Au-13 Chirality Singlet oxygen Synchrotron radiation x-ray diffraction (xrd) |
| DOI | 10.1007/s12274-017-1935-2 |
| 通讯作者 | Li, gao(gaoli@dicp.ac.cn) |
| 英文摘要 | In this study, 1,2-bis(diphenylphosphino)ethane (dppe) ligands are used to synthesize gold nanoclusters with an icosahedral au-13 core. the nanoclusters are characterized and formulated as [au-13(dppe)5cl(2)]cl-3 using synchrotron radiation x-ray diffraction, uv/vis absorption spectroscopy, electrospray ionization mass spectrometry, and density functional theory (dft) calculations. the bidentate feature of dppe ligands and the positions of coordinating surface gold atoms induce a helical arrangement that forms a propeller-like structure, which reduces the symmetry of the gold nanocluster to c-1. therefore, dppe ligands perform as a directing agent to create chiral an ansa metallamacrocycle [au-13(dppe)(5)cl-2](3+) nanocluster, as confirmed by simulated electronic circular dichroism spectrum. the highest occupied molecular orbital (homo)-lowest unoccupied molecular orbital (lumo) gap of the [au-13(dppe)(5)cl-2](3+) cluster is determined as approx. 1.9 ev, and further confirmed by ultraviolet photoemission spectroscopy analysis and dft simulation. furthermore, the photoactivity of [au-13(dppe)(5)cl-2](3+) is investigated, with the nanocluster shown to possess near-infrared photoluminescence properties, which can be employed for o-1(2) photogeneration. the quantum yield of o-1(2) photogeneration using the [au-13(dppe)(5)cl-2](3+) nanocluster is up to 0.71, which is considerably higher than those of anthracene (an organic dye), and au-25 and au-38 nanoclusters. |
| WOS关键词 | NUMBER AU-13 CLUSTERS ; AEROBIC OXIDATION ; ANDERSON-TYPE ; EXCHANGE ; LIGANDS ; NANOPARTICLES ; PHOTOCATALYST ; GENERATION ; CHEMISTRY ; CATALYSIS |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
| 语种 | 英语 |
| 出版者 | TSINGHUA UNIV PRESS |
| WOS记录号 | WOS:000449842500002 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373114 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Li, Gao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Stanford Univ, Dept Chem Engn, SUNCAT Ctr Interface Sci & Catalysis, 443 Via Ortega, Stanford, CA 94305 USA 4.US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA 5.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jiangwei,Zhou, Yang,Zheng, Kai,et al. Diphosphine-induced chiral propeller arrangement of gold nanoclusters for singlet oxygen photogeneration[J]. Nano research,2018,11(11):5787-5798. |
| APA | Zhang, Jiangwei.,Zhou, Yang.,Zheng, Kai.,Abroshan, Hadi.,Kauffman, Douglas R..,...&Li, Gao.(2018).Diphosphine-induced chiral propeller arrangement of gold nanoclusters for singlet oxygen photogeneration.Nano research,11(11),5787-5798. |
| MLA | Zhang, Jiangwei,et al."Diphosphine-induced chiral propeller arrangement of gold nanoclusters for singlet oxygen photogeneration".Nano research 11.11(2018):5787-5798. |
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来源：大连化学物理研究所
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