Assembly of heteropoly acid into localized porous structures for in situ preparation of silver and polypyrrole nanoparticles
文献类型：期刊论文
| 作者 | Liang, Jing1; Yu, Lei2; Zhang, Jiangyong1; Zhao, Shixiong3; Zhang, Jiejing1; Zhang, Jianfeng1 |
| 刊名 | Rsc advances
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:64页码:36558-36562 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c8ra07939k |
| 通讯作者 | Liang, jing(liangjing@jlau.edu.cn) |
| 英文摘要 | A simple and facile method to fabricate porous films which were locally patterned by heteropoly acid was developed in this study. the mixture of poly(methyl methacrylate) and stabilizer dichloromethane solution which contains heteropoly acid aqueous solution, prepared through shaking, was applied to fabricate a reversed microemulsion. after spreading and evaporating the solvent of microemulsion on a glass slide, an ordered honeycomb film was produced by incorporation of heteropoly acid in the cavities. the locally anchored heteropoly acid could be readily applied for the selective modification of the porous films through the in situ chemical reactions in the cavities with the additive agents. the silver nanoparticles were in situ prepared via the reduction of silver ions by reduced state h3pw12o40, and the polypyrrole spheres were locally obtained through the oxidative polymerization of pyrrole catalyzed by h3pmo12o40 in the cavities. considering that water-soluble molecules and nanoparticles were universally suitable for the present strategy, the reported approach opened up an efficient way for patterning organically incompatible components on porous polymer films via the assembly of microemulsion droplet carriers to fabricate multi-functional hybrid surface structures. |
| WOS关键词 | SELF-ORGANIZED HONEYCOMB ; BREATH FIGURES ; POLYMER-FILM ; FABRICATION ; ARRAYS ; MORPHOLOGY ; ANION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000449704100019 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373117 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Liang, Jing |
| 作者单位 | 1.Jilin Agr Univ, Coll Life Sci, Changchun 130118, Jilin, Peoples R China 2.Jilin Rad & TV Univ, Changchun 130022, Jilin, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, Jing,Yu, Lei,Zhang, Jiangyong,et al. Assembly of heteropoly acid into localized porous structures for in situ preparation of silver and polypyrrole nanoparticles[J]. Rsc advances,2018,8(64):36558-36562. |
| APA | Liang, Jing,Yu, Lei,Zhang, Jiangyong,Zhao, Shixiong,Zhang, Jiejing,&Zhang, Jianfeng.(2018).Assembly of heteropoly acid into localized porous structures for in situ preparation of silver and polypyrrole nanoparticles.Rsc advances,8(64),36558-36562. |
| MLA | Liang, Jing,et al."Assembly of heteropoly acid into localized porous structures for in situ preparation of silver and polypyrrole nanoparticles".Rsc advances 8.64(2018):36558-36562. |
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来源：大连化学物理研究所
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