Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes
文献类型：期刊论文
| 作者 | Lei, Xin1,2; Kong, Xiangtao1; Zhao, Zhi1; Zhang, Bingbing1,2; Dai, Dongxu1; Yang, Xueming1; Jiang, Ling1 |
| 刊名 | Physical chemistry chemical physics
 |
| 出版日期 | 2018-10-28 |
| 卷号 | 20期号:40页码:9 |
| ISSN号 | 1463-9076 |
| DOI | 10.1039/c8cp03672a |
| 通讯作者 | Jiang, ling(ljiang@dicp.ac.cn) |
| 英文摘要 | Cryogenic ion-trap infrared photodissociation spectroscopy combined with a dielectric barrier discharge source was constructed to establish the general trends in the stepwise growth motif of trimethylamine (tma)(n)(+) complexes. the results showed a strong preference for the formation of a stable charge-shared nn type (tma)(2)(+) ion core over the proton-transferred chn type ion core, evidencing that the source condition has a remarkable effect on the kinetic stability of isomers. a maximum of four tma molecules are located perpendicularly to the nn axis of the charge-shared (tma)(2)(+) ion core. in the n = 7 and 8 clusters, the subsequent two tma molecules are located at each end of the nn axis of the (tma)(2)(+) ion core, completing the first coordination shell. starting at n = 9, the additional tma molecules form a second solvation shell, and the cluster spectra show similarities to the solution phase spectrum of aqueous tma. |
| WOS关键词 | PHOTOELECTRON-SPECTROSCOPY ; VIBRATIONAL SPECTROSCOPY ; BONDED CLUSTERS ; DIMER ; ANION ; NUCLEATION ; MOLECULES ; CHEMISTRY ; DIANIONS ; SPECTRUM |
| WOS研究方向 | Chemistry ; Physics |
| WOS类目 | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000448345800003 |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373136 |
| 专题 | 大连化学物理研究所 |
| 通讯作者 | Jiang, Ling |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lei, Xin,Kong, Xiangtao,Zhao, Zhi,et al. Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes[J]. Physical chemistry chemical physics,2018,20(40):9. |
| APA | Lei, Xin.,Kong, Xiangtao.,Zhao, Zhi.,Zhang, Bingbing.,Dai, Dongxu.,...&Jiang, Ling.(2018).Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes.Physical chemistry chemical physics,20(40),9. |
| MLA | Lei, Xin,et al."Infrared photodissociation spectroscopy of cold cationic trimethylamine complexes".Physical chemistry chemical physics 20.40(2018):9. |
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来源：大连化学物理研究所
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