Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds
文献类型:期刊论文
作者 | Huo, Jingfeng1; Xue, Yazhen1; Wang, Jianbo1,2 |
刊名 | Chemical communications
![]() |
出版日期 | 2018-11-07 |
卷号 | 54期号:86页码:12266-12269 |
ISSN号 | 1359-7345 |
DOI | 10.1039/c8cc07764a |
通讯作者 | Wang, jianbo(wangjb@pku.edu.cn) |
英文摘要 | A cu(i)-catalyzed aminoborylation reaction of styrenes is reported. in this transformation, diazo compounds are used as the electrophilic amination agent. the in situ generated benzylcopper species is trapped by the electrophilic nitrogen terminus of the diazo substrate to afford borylated hydrazones in a regioselective manner. |
WOS关键词 | UNACTIVATED TERMINAL ALKENES ; AMINOBORATION ; INSERTION ; ESTERS ; ELECTROPHILES ; NITROGEN ; BONDS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Multidisciplinary |
语种 | 英语 |
WOS记录号 | WOS:000448501400029 |
出版者 | ROYAL SOC CHEMISTRY |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373150 |
专题 | 大连化学物理研究所 |
通讯作者 | Wang, Jianbo |
作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
推荐引用方式 GB/T 7714 | Huo, Jingfeng,Xue, Yazhen,Wang, Jianbo. Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds[J]. Chemical communications,2018,54(86):12266-12269. |
APA | Huo, Jingfeng,Xue, Yazhen,&Wang, Jianbo.(2018).Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds.Chemical communications,54(86),12266-12269. |
MLA | Huo, Jingfeng,et al."Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds".Chemical communications 54.86(2018):12266-12269. |
入库方式: iSwitch采集
来源:大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。