中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds

文献类型:期刊论文

作者Huo, Jingfeng1; Xue, Yazhen1; Wang, Jianbo1,2
刊名Chemical communications
出版日期2018-11-07
卷号54期号:86页码:12266-12269
ISSN号1359-7345
DOI10.1039/c8cc07764a
通讯作者Wang, jianbo(wangjb@pku.edu.cn)
英文摘要A cu(i)-catalyzed aminoborylation reaction of styrenes is reported. in this transformation, diazo compounds are used as the electrophilic amination agent. the in situ generated benzylcopper species is trapped by the electrophilic nitrogen terminus of the diazo substrate to afford borylated hydrazones in a regioselective manner.
WOS关键词UNACTIVATED TERMINAL ALKENES ; AMINOBORATION ; INSERTION ; ESTERS ; ELECTROPHILES ; NITROGEN ; BONDS
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
WOS记录号WOS:000448501400029
出版者ROYAL SOC CHEMISTRY
URI标识http://www.irgrid.ac.cn/handle/1471x/2373150
专题大连化学物理研究所
通讯作者Wang, Jianbo
作者单位1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Huo, Jingfeng,Xue, Yazhen,Wang, Jianbo. Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds[J]. Chemical communications,2018,54(86):12266-12269.
APA Huo, Jingfeng,Xue, Yazhen,&Wang, Jianbo.(2018).Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds.Chemical communications,54(86),12266-12269.
MLA Huo, Jingfeng,et al."Regioselective copper-catalyzed aminoborylation of styrenes with bis(pinacolato)diboron and diazo compounds".Chemical communications 54.86(2018):12266-12269.

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来源:大连化学物理研究所

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