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Structures of the zeta and zeta ' phases in the ag-ga system

文献类型:期刊论文

作者Zhang, Y; Liu, QL; Li, JB; Liang, JK; Luo, J; Liu, FS; Xiao, YG; Rao, GH
刊名Journal of alloys and compounds
出版日期2005-08-16
卷号399期号:1-2页码:155-159
关键词Zeta-phase Zeta '-phase structure determination X-ray powder diffraction
ISSN号0925-8388
DOI10.1016/j.jallcom.2005.03.025
通讯作者Liang, jk(jkliang@aphy.iphy.ac.cn)
英文摘要The crystal structures of the zeta-phase and zeta'-phase have been determined by x-ray powder diffraction and refined by rietveld method. the space group of the zeta'-phase is p (6) over bar 2m with the lattice parameters a = 7.7710(1) and c = 2.8788(1) angstrom. the ideal formula is ag2ga (real composition ag2+xga1-x, x = 0.16) and the chemical formula per unit cell is z = 3. six ag atoms occupy the 3g positions with x = 0.63970(8) and the 3f positions with x = 0.30347(9), respectively. three ga atoms occupy the 2c and the 1b sites. the zeta-phase is obtained by quenching the sample containing 20 at.% ga from 500 degrees c to room temperature. its space group is close-packed hexagonal, p6(3)/mmc, and the lattice parameters are a = 2.8818(1) and c = 4.6956(1) angstrom. there are 2 atoms (1.5ag + 0.5ga) per unit cell, which occupy the 2c site statistically. the relation between the structures of the zeta- and zeta'-phase is discussed. (c) 2005 elsevier b.v. all rights reserved.
WOS关键词SILVER-GALLIUM ; EQUILIBRIUM DIAGRAM ; ALLOYS ; DIFFRACTION ; REFINEMENT ; REGION ; COPPER
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:000230614600028
出版者ELSEVIER SCIENCE SA
URI标识http://www.irgrid.ac.cn/handle/1471x/2373609
专题物理研究所
通讯作者Liang, JK
作者单位1.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China
2.Acad Sinica, Int Ctr Mat Phys, Shenyang 110016, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Y,Liu, QL,Li, JB,et al. Structures of the zeta and zeta ' phases in the ag-ga system[J]. Journal of alloys and compounds,2005,399(1-2):155-159.
APA Zhang, Y.,Liu, QL.,Li, JB.,Liang, JK.,Luo, J.,...&Rao, GH.(2005).Structures of the zeta and zeta ' phases in the ag-ga system.Journal of alloys and compounds,399(1-2),155-159.
MLA Zhang, Y,et al."Structures of the zeta and zeta ' phases in the ag-ga system".Journal of alloys and compounds 399.1-2(2005):155-159.

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来源:物理研究所

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