The crystal structure and absolute configuration of (+)-1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-2-butanol of diastercoisomer a
文献类型：期刊论文
| 作者 | Dou Shiqi1; Yao Jia Xing2; Li Zhengming3; Dong Liwen3 |
| 刊名 | Acta physico-chimica sinica
 |
| 出版日期 | 1987 |
| 卷号 | 3期号:1页码:74-78 |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/pku.whxb19870113 |
| 通讯作者 | Dou shiqi() |
| 英文摘要 | The crystal of (+) a triadimenol (baylan) belongs to monoclinic system with space group c-3(2)-p2(1) and cell totrameters; a = 10.543(1) angstrom, b=8.202(1) angstrom, c = 9.778(1) angstrom, beta = 113.042(7)degrees. there are two molecules in each unit cell, z=2. the x-ray diffraction data were collected on pw-1100 four-circle diffractometer, with cuka radition. the number of independent diffraction data amounts to 1610, of which 1524 are observable reflections. the crystal structure has been determined by direct method (rantan) and refitted hy full-matrix least-square method to r=0.065. the absolute configuration has been assigned by direct measurement of 18 enantiomer sensitive bijvoet reflection pairs. x-ray structure analysis shows that absolute configuration of (+)-a triadimenol is 1r,2s the triazole ring has an aromatic property. |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Physical |
| 语种 | 英语 |
| WOS记录号 | WOS:000207569100013 |
| 出版者 | PEKING UNIV PRESS |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2373730 |
| 专题 | 物理研究所 |
| 通讯作者 | Dou Shiqi |
| 作者单位 | 1.Acad Sinica, Inst Biophys, Beijing 100080, Peoples R China 2.Acad Sinica, Inst Phys, Beijing 100080, Peoples R China 3.Nankai Univ, Inst Elemento Organ Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dou Shiqi,Yao Jia Xing,Li Zhengming,et al. The crystal structure and absolute configuration of (+)-1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-2-butanol of diastercoisomer a[J]. Acta physico-chimica sinica,1987,3(1):74-78. |
| APA | Dou Shiqi,Yao Jia Xing,Li Zhengming,&Dong Liwen.(1987).The crystal structure and absolute configuration of (+)-1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-2-butanol of diastercoisomer a.Acta physico-chimica sinica,3(1),74-78. |
| MLA | Dou Shiqi,et al."The crystal structure and absolute configuration of (+)-1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-2-butanol of diastercoisomer a".Acta physico-chimica sinica 3.1(1987):74-78. |
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