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Can p,p '-dimercaptoazobisbenzene be produced from p-aminothiophenol by surface photochemistry reaction in the junctions of a ag nanoparticle-molecule-ag (or au) film?

文献类型:期刊论文

作者Huang, Yingzhou1,2; Fang, Yurui1; Yang, Zhilin3; Sun, Mengtao1
刊名Journal of physical chemistry c
出版日期2010-10-28
卷号114期号:42页码:18263-18269
ISSN号1932-7447
DOI10.1021/jp107305z
通讯作者Sun, mengtao(mtsun@aphy.iphy.ac.cn)
英文摘要In this study, we attempt to experimentally address the question of whether p,p'-dimercaptoazobisbenzene (dmab) can be produced from p-aminothiophenol (patp) by surface photochemistry reaction in the junctions of a ag nanoparticle-molecule-ag (or au) film. first, utilizing surface-enhanced raman scattering (sers) spectra, we provide experimental and theoretical evidence that dmab can be produced from patp by surface photochemistry reaction in the junctions of a ag nanoparticle-molecule-ag film. second, we investigate the sers spectra utilizing both experimental and theoretical approaches, ultimately revealing that dmab cannot be produced from patp in the junctions of a ag nanoparticle-molecule-au film. the electromagnetic enhancements are estimated with three-dimensional finite-difference time domain methods, which are about 9 x 10(5) times in the junctions of ag nanoparticle-patp-ag/au films.
WOS关键词ENHANCED RAMAN-SCATTERING ; CHARGE-TRANSFER ; FIELD ENHANCEMENT ; SILVER ; SPECTROSCOPY ; GOLD ; SIMULATION ; SERS
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000283110700036
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2373740
专题物理研究所
通讯作者Sun, Mengtao
作者单位1.Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China
2.Chongqing Univ, Dept Appl Phys, Chongqing 400044, Peoples R China
3.Xiamen Univ, Dept Phys, Xiamen 361005, Peoples R China
推荐引用方式
GB/T 7714
Huang, Yingzhou,Fang, Yurui,Yang, Zhilin,et al. Can p,p '-dimercaptoazobisbenzene be produced from p-aminothiophenol by surface photochemistry reaction in the junctions of a ag nanoparticle-molecule-ag (or au) film?[J]. Journal of physical chemistry c,2010,114(42):18263-18269.
APA Huang, Yingzhou,Fang, Yurui,Yang, Zhilin,&Sun, Mengtao.(2010).Can p,p '-dimercaptoazobisbenzene be produced from p-aminothiophenol by surface photochemistry reaction in the junctions of a ag nanoparticle-molecule-ag (or au) film?.Journal of physical chemistry c,114(42),18263-18269.
MLA Huang, Yingzhou,et al."Can p,p '-dimercaptoazobisbenzene be produced from p-aminothiophenol by surface photochemistry reaction in the junctions of a ag nanoparticle-molecule-ag (or au) film?".Journal of physical chemistry c 114.42(2010):18263-18269.

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