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Substrate-, wavelength-, and time-dependent plasmon-assisted surface catalysis reaction of 4-nitrobenzenethiol dimerizing to p,p '-dimercaptoazobenzene on au, ag, and cu films

文献类型:期刊论文

作者Dong, Bin1,2; Fang, Yurui1; Chen, Xiaowei3; Xu, Hongxing1,4; Sun, Mengtao1
刊名Langmuir
出版日期2011-09-06
卷号27期号:17页码:10677-10682
ISSN号0743-7463
DOI10.1021/la2018538
通讯作者Sun, mengtao(mtsun@aphy.iphy.ac.cn)
英文摘要In this article, we experimentally investigate the substrate, wavelength, and time dependence of the plasmon-assisted surface-catalyzed dimerization of 4-nitrobenzenethiol to form p,p'-dimercaptoazobenzene on au, ag, and cu films. we provide direct experimental evidence that surface plasmon resonance plays the most important role in these surface-catalyzed reactions. it is found that the reaction is strongly dependent on the substrate, the wavelength of the laser, and the reaction timescales. our experimental results revealed that optimal experimental conditions can be rationally chosen to control (accelerate or restrain) this reaction. the experimental results are also confirmed by theoretical calculations.
WOS关键词SCANNING TUNNELING MICROSCOPE ; P-AMINOTHIOPHENOL ; CHAIN POLYMERIZATION ; NANOSCALE CONTROL ; COUPLING REACTION ; ENHANCED RAMAN ; MOLECULE ; NANOPARTICLES ; SPECTROSCOPY ; JUNCTIONS
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Multidisciplinary ; Chemistry, Physical ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000294373300043
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2373769
专题物理研究所
通讯作者Sun, Mengtao
作者单位1.Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China
2.Dalian Nationalities Univ, Sch Sci, Dalian 116600, Peoples R China
3.Univ Cadiz, Fac Ciencias, Dept Ciencia Mat Ingn Met & Quim Inorgan, E-11510 Cadiz, Spain
4.Lund Univ, Div Solid State Phys, S-22100 Lund, Sweden
推荐引用方式
GB/T 7714
Dong, Bin,Fang, Yurui,Chen, Xiaowei,et al. Substrate-, wavelength-, and time-dependent plasmon-assisted surface catalysis reaction of 4-nitrobenzenethiol dimerizing to p,p '-dimercaptoazobenzene on au, ag, and cu films[J]. Langmuir,2011,27(17):10677-10682.
APA Dong, Bin,Fang, Yurui,Chen, Xiaowei,Xu, Hongxing,&Sun, Mengtao.(2011).Substrate-, wavelength-, and time-dependent plasmon-assisted surface catalysis reaction of 4-nitrobenzenethiol dimerizing to p,p '-dimercaptoazobenzene on au, ag, and cu films.Langmuir,27(17),10677-10682.
MLA Dong, Bin,et al."Substrate-, wavelength-, and time-dependent plasmon-assisted surface catalysis reaction of 4-nitrobenzenethiol dimerizing to p,p '-dimercaptoazobenzene on au, ag, and cu films".Langmuir 27.17(2011):10677-10682.

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来源:物理研究所

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