中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Neutral excitons and metastable charged polarons in 5,5 '-bis-(2-phenylethylnyl)-2,2 '-bithienyl

文献类型:期刊论文

作者Kim, YH; Deng, TZ; Feng, BH; Nie, YX; Zhao, ZX; Zimmer, H; Sudsuansri, K
刊名Physical review b
出版日期1998-04-15
卷号57期号:15页码:9336-9342
ISSN号1098-0121
通讯作者Kim, yh()
英文摘要We have carried out steady-state photoinduced infrared-absorption measurements on the newly synthesized organic molecule 5,5'-bis-(2-phenylethylnyl)-2,2'-bithienyl (phetbt). we have found that the dominant elementary excitations in phetbt are wannier-type neutral excitons formed between electrons and holes strongly localized in adjacent intramolecular or intermolecular c=c sites. we observed that charge carriers which do not undergo direct radiative recombination are self-localized by forming metastable charged polarons. we have observed two different charge distributions on the polaron site; one is polaronlike for t < 120 k, and the other is bipolaronlike at t> 120 k. we suggest that the charge trap centers are provided by the large polarizability of the localized pi' dimers in the c=c site. [s0163-1829(98)04203-9].
WOS关键词CONDUCTING POLYMERS ; INFRARED ACTIVITY ; POLY(PHENYLENE VINYLENE) ; CONJUGATED POLYMERS ; POLYACETYLENE ; MODEL ; STATE ; PHOTOGENERATION ; PHOTOEXCITATION ; OLIGOTHIOPHENES
WOS研究方向Physics
WOS类目Physics, Condensed Matter
语种英语
WOS记录号WOS:000073219900085
出版者AMER PHYSICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2373819
专题物理研究所
通讯作者Kim, YH
作者单位1.Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
2.Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA
推荐引用方式
GB/T 7714
Kim, YH,Deng, TZ,Feng, BH,et al. Neutral excitons and metastable charged polarons in 5,5 '-bis-(2-phenylethylnyl)-2,2 '-bithienyl[J]. Physical review b,1998,57(15):9336-9342.
APA Kim, YH.,Deng, TZ.,Feng, BH.,Nie, YX.,Zhao, ZX.,...&Sudsuansri, K.(1998).Neutral excitons and metastable charged polarons in 5,5 '-bis-(2-phenylethylnyl)-2,2 '-bithienyl.Physical review b,57(15),9336-9342.
MLA Kim, YH,et al."Neutral excitons and metastable charged polarons in 5,5 '-bis-(2-phenylethylnyl)-2,2 '-bithienyl".Physical review b 57.15(1998):9336-9342.

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