A facile surfactant-assisted reflux method for the synthesis of single-crystalline sb2te3 nanostructures with enhanced thermoelectric performance
文献类型：期刊论文
| 作者 | Yang, Heng Quan1,2; Miao, Lei1,5; Liu, Cheng Yan1; Li, Chao3; Honda, Sawao4; Iwamoto, Yuji4; Huang, Rong3; Tanemura, Sakae1 |
| 刊名 | Acs applied materials & interfaces
 |
| 出版日期 | 2015-07-08 |
| 卷号 | 7期号:26页码:14263-14271 |
| 关键词 | Antimony telluride Growth mechanism Reflux method Thermoelectric materials Transport properties |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.5b02504 |
| 通讯作者 | Miao, lei(miaolei@ms.giec.ac.cn) |
| 英文摘要 | Antimony telluride (sb2te3) and its based alloys are of importance to p-type semiconductors for thermoelectric applications near room temperature. herein, we report a simple, low-energy intensive, and scalable surfactant-assisted reflux method for the synthesis of sb2te3 nanoparticles in the solvent ethylene glycol (eg) at low temperatures (120-180 degrees c). the formation mechanism of platelike sb2te3 nanoparticles is proposed. also, it is found that the size, shape, and chemical composition of the products could be controlled by the introduction of organic surfactants (ctab, pvp, etc.) or inorganic salts (edta-na-2, naoh, etc.). additionally, the collected sb2te3 nanoparticles were further fabricated into nanostructured pellets using cold-compaction and annealing techniques. low resistivity [(7.37-19.4) x 10(-6) omega m], moderate seebeck coefficient (103-141 mu v k-1), and high power factor (10-16 x 10(-4) w m(-1) k-2) have been achieved in our sb2te3-nanostructured bulk materials. the relatively low thermal conductivity (1.32-1.55 w m(-1) k-1) is attained in the nanobulk made of pvp-modified nanoparticles, and values of zt in the range of 0.24-0.37 are realized at temperatures ranging from 50 to 200 degrees c. our researches set forth a new avenue in promoting practical applications of sb2te3-based thermoelectric power generation or cooling devices. |
| WOS关键词 | FIGURE-OF-MERIT ; ANTIMONY TELLURIDE ; SOLVOTHERMAL SYNTHESIS ; TRANSPORT-PROPERTIES ; HYDROTHERMAL SYNTHESIS ; STRUCTURAL-CHARACTERIZATION ; BULK THERMOELECTRICS ; NANOWIRES ; PHASE ; MECHANISM |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| WOS类目 | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000357963700012 |
| 出版者 | AMER CHEMICAL SOC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374054 |
| 专题 | 物理研究所 |
| 通讯作者 | Miao, Lei |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.E China Normal Univ, Minist Educ, Key Lab Polarized Mat & Devices, Shanghai 200062, Peoples R China 4.Nagoya Inst Technol, Grad Sch Engn, Dept Frontier Mat, Showa Ku, Nagoya, Aichi 4668555, Japan 5.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guilin 51004, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Heng Quan,Miao, Lei,Liu, Cheng Yan,et al. A facile surfactant-assisted reflux method for the synthesis of single-crystalline sb2te3 nanostructures with enhanced thermoelectric performance[J]. Acs applied materials & interfaces,2015,7(26):14263-14271. |
| APA | Yang, Heng Quan.,Miao, Lei.,Liu, Cheng Yan.,Li, Chao.,Honda, Sawao.,...&Tanemura, Sakae.(2015).A facile surfactant-assisted reflux method for the synthesis of single-crystalline sb2te3 nanostructures with enhanced thermoelectric performance.Acs applied materials & interfaces,7(26),14263-14271. |
| MLA | Yang, Heng Quan,et al."A facile surfactant-assisted reflux method for the synthesis of single-crystalline sb2te3 nanostructures with enhanced thermoelectric performance".Acs applied materials & interfaces 7.26(2015):14263-14271. |
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