Pb5ga6zns15: a noncentrosymmetric framework with chains of t2-supertetrahedra
文献类型：期刊论文
| 作者 | Duan, Rui-Huan1,2; Yu, Ju-Song1,2; Lin, Hua1; Zheng, Yu-Jun1,2; Zhao, Hua-Jun3; Huang-Fu, Shang-Xiong4; Khan, Muhammad Ali1,2; Chen, Ling1; Wu, Li-Ming1 |
| 刊名 | Dalton transactions
 |
| 出版日期 | 2016-08-21 |
| 卷号 | 45期号:31页码:12288-12291 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c6dt02404a |
| 通讯作者 | Wu, li-ming(liming_wu@fjirsm.ac.cn) |
| 英文摘要 | A novel noncentrosysmmetric sulfide, pb5ga6zns15 (1), was synthesized for the first time. its crystal structure revealed the presence of [gas2](infinity)(-) (chain 1, chains of [gas4](5-) tetrahedra) and [ga4s9](infinity)(6-) (chain 2, chains of t2-supertetrahedra) connected by isolated [zns4](6-) tetrahedra. structure correlation with the network constructed solely using chain 1 (pb(4)ga(4)geq(12)-type) is discussed. pb5ga6zns15 was calculated to have a suitable static briefringence (delta n) of 0.1137, and a large nonlinear optical susceptibility d(31) of 58.32 pm v-1 at a wavelength of 2.05 mu m (0.6 ev), much higher than that of the benchmark aggas2 (18.14 pm v-1). |
| WOS关键词 | 2ND-HARMONIC GENERATION RESPONSE ; NONLINEAR-OPTICAL PROPERTIES ; LASER DAMAGE THRESHOLD ; METAL CHALCOGENIDES ; GE ; CRYSTALS ; AGGAS2 ; PR ; SE ; SN |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| WOS记录号 | WOS:000381480900003 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374376 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Li-Ming |
| 作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Zunyi Normal Coll, Sch Chem & Chem Engn, Lab Appl Res Characterist Resources North Guizhou, Zunyi 563002, Guizhou, Peoples R China 4.Univ Zurich, Inst Phys, Winterthurerstr 190, CH-8057 Zurich, Switzerland |
| 推荐引用方式 GB/T 7714 | Duan, Rui-Huan,Yu, Ju-Song,Lin, Hua,et al. Pb5ga6zns15: a noncentrosymmetric framework with chains of t2-supertetrahedra[J]. Dalton transactions,2016,45(31):12288-12291. |
| APA | Duan, Rui-Huan.,Yu, Ju-Song.,Lin, Hua.,Zheng, Yu-Jun.,Zhao, Hua-Jun.,...&Wu, Li-Ming.(2016).Pb5ga6zns15: a noncentrosymmetric framework with chains of t2-supertetrahedra.Dalton transactions,45(31),12288-12291. |
| MLA | Duan, Rui-Huan,et al."Pb5ga6zns15: a noncentrosymmetric framework with chains of t2-supertetrahedra".Dalton transactions 45.31(2016):12288-12291. |
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来源：中国科学院大学
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