Cobalt(iii)-catalyzed c-c coupling of arenes with 7-oxabenzonorbornadiene and 2-vinyloxirane via c-h activation
文献类型:期刊论文
作者 | Kong, Lingheng1,2; Yu, Songjie1; Tang, Guodong1; Wang, He1; Zhou, Xukai1,2; Li, Xingwei1 |
刊名 | Organic letters
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出版日期 | 2016-08-05 |
卷号 | 18期号:15页码:3802-3805 |
ISSN号 | 1523-7060 |
DOI | 10.1021/acs.orglett.6b01806 |
通讯作者 | Li, xingwei(xwli@dicp.ac.cn) |
英文摘要 | Co(iii)-catalyzed mild c-c couplings of arenes with strained rings such as 7-oxabenzonorbomadienes and 2-vinyloxirane have been realized. the transformation is proposed to undergo ortho c-h activation, olefin insertion, and subsequent beta-oxygen elimination. a broad range of synthetically useful functional groups are compatible, thus providing a new entry to access diversely 2-functionalized indoles. |
WOS关键词 | N-TYPE REACTIONS ; ALLYLIC ALCOHOLS ; BOND ACTIVATION ; MULTISUBSTITUTED ISOQUINOLINES ; INTERNAL ALKYNES ; INDOLE SYNTHESIS ; ALLYLATION ; FUNCTIONALIZATION ; AMIDATION ; ACCESS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
WOS记录号 | WOS:000381236300074 |
出版者 | AMER CHEMICAL SOC |
URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374413 |
专题 | 中国科学院大学 |
通讯作者 | Li, Xingwei |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Kong, Lingheng,Yu, Songjie,Tang, Guodong,et al. Cobalt(iii)-catalyzed c-c coupling of arenes with 7-oxabenzonorbornadiene and 2-vinyloxirane via c-h activation[J]. Organic letters,2016,18(15):3802-3805. |
APA | Kong, Lingheng,Yu, Songjie,Tang, Guodong,Wang, He,Zhou, Xukai,&Li, Xingwei.(2016).Cobalt(iii)-catalyzed c-c coupling of arenes with 7-oxabenzonorbornadiene and 2-vinyloxirane via c-h activation.Organic letters,18(15),3802-3805. |
MLA | Kong, Lingheng,et al."Cobalt(iii)-catalyzed c-c coupling of arenes with 7-oxabenzonorbornadiene and 2-vinyloxirane via c-h activation".Organic letters 18.15(2016):3802-3805. |
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来源:中国科学院大学
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