中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Formation of coronene clusters in concentration and temperature controlled two-dimensional porous network

文献类型:期刊论文

作者Dai, Hongliang1,2; Yi, Wenjing3; Deng, Ke1,2; Wang, Hua3; Zeng, Qingdao1,2
刊名Acs applied materials & interfaces
出版日期2016-08-17
卷号8期号:32页码:21095-21100
关键词Concentration regulation Temperature regulation Coronene cluster Honeycomb network Scanning tunneling microscopy
ISSN号1944-8244
DOI10.1021/acsami.6b06638
通讯作者Deng, ke(kdeng@nanoctr.cn) ; Wang, hua(hwang@henu.edu.cn) ; Zeng, qingdao(zengqd@nanoctr.cn)
英文摘要In this research, with the assistance of scanning tunneling microscopy (stm), we observed the two-dimensional (2d) self-assembly transition of a star-shaped oligofluorene derivative (stof) from disordered structure to honeycomb network by adjusting stof concentration in solution. by, introducing guest molecules coronene (cor), we for the first time achieved novel triangle-shaped cor trimers on liquid/highly oriented pyrolytic graphite (hopg) interface in both honeycomb network and the disordered structure. in thermal tests, the cor/stof disorder system underwent a structural conformation to form well-ordered ladder structures, while the cor/stof honeycomb system remained the perfect hexagonal network with cor trimers included in the cavities. density functional theory (dft). calculations have been employed to investigate the forming mechanism of the molecular nanoarrays. these studies are expected to enhance controlling, on 2d self,assembly and provide a facial approach toward constructing on-surface molecular clusters.
WOS关键词SCANNING-TUNNELING-MICROSCOPY ; LIQUID-SOLID INTERFACE ; STAR-SHAPED OLIGOFLUORENES ; FABRICATION ; MOLECULES ; TEMPLATE ; STM ; TRANSITION ; PEPTIDES ; DYNAMICS
WOS研究方向Science & Technology - Other Topics ; Materials Science
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
WOS记录号WOS:000381715900069
出版者AMER CHEMICAL SOC
URI标识http://www.irgrid.ac.cn/handle/1471x/2374415
专题中国科学院大学
通讯作者Deng, Ke; Wang, Hua; Zeng, Qingdao
作者单位1.Natl Ctr Nanosci & Technol NCNST, CAS Ctr Excellence Nanosci, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Henan Univ, Engn Res Ctr Nanomat, Kaifeng 475004, Peoples R China
推荐引用方式
GB/T 7714
Dai, Hongliang,Yi, Wenjing,Deng, Ke,et al. Formation of coronene clusters in concentration and temperature controlled two-dimensional porous network[J]. Acs applied materials & interfaces,2016,8(32):21095-21100.
APA Dai, Hongliang,Yi, Wenjing,Deng, Ke,Wang, Hua,&Zeng, Qingdao.(2016).Formation of coronene clusters in concentration and temperature controlled two-dimensional porous network.Acs applied materials & interfaces,8(32),21095-21100.
MLA Dai, Hongliang,et al."Formation of coronene clusters in concentration and temperature controlled two-dimensional porous network".Acs applied materials & interfaces 8.32(2016):21095-21100.

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来源:中国科学院大学

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