Ammonium aminodiboranate: a long-sought isomer of diammoniate of diborane and ammonia borane dimer
文献类型：期刊论文
| 作者 | Chen, Weidong1,2; Yu, Haibo3; Wu, Guotao1; He, Teng1; Li, Zhao1,2; Guo, Zaiping4; Liu, Huakun4; Huang, Zhenguo4; Chen, Ping1,5,6 |
| 刊名 | Chemistry-a european journal
 |
| 出版日期 | 2016-06-01 |
| 卷号 | 22期号:23页码:7727-7729 |
| 关键词 | Aminodiboranes Boranes Boron Hydrogen bonds |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201601375 |
| 通讯作者 | Huang, zhenguo(zhenguo@uow.edu.au) ; Chen, ping(pchen@dicp.ac.cn) |
| 英文摘要 | Ammonium minodiboranate ([nh4] [bh3nh2bh3]) is a long-sought isomer of diammoniate of diborane ([nh3bh2nh3][bh4]) and ammonia borane (nh3bh3) dimer. our results show that [nh4][bh3nh2bh3] is stable in tetrahydrofuran at -18 degrees c and decomposes rapidly to nh3bh2nh2bh3 and h-2 at elevated temperatures. the decomposition pathway is dictated by the dihydrogen bonding between h delta+ on nh4+ and h delta- on bh3, as confirmed by theoretical calculations. this is in contrast to the interconversion between [nh3bh2nh3][bh4] and (nh3bh3)(2), although all three have dihydrogen bonds and the same stoichiometry. |
| WOS关键词 | INORGANIC BUTANE ANALOG ; CHEMICAL EVIDENCE ; BOROHYDRIDE ; NH3BH2NH2BH3 ; EVOLUTION ; HYDROGEN ; HYDRIDES ; RELEASE ; SODIUM ; SALTS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000380267100009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374516 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Huang, Zhenguo; Chen, Ping |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Lab Clean Energy, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Univ Wollongong, Sch Chem, Wollongong, NSW 2522, Australia 4.Univ Wollongong, ISEM, Wollongong, NSW 2522, Australia 5.Chinese Acad Sci, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 6.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat IChEM, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Weidong,Yu, Haibo,Wu, Guotao,et al. Ammonium aminodiboranate: a long-sought isomer of diammoniate of diborane and ammonia borane dimer[J]. Chemistry-a european journal,2016,22(23):7727-7729. |
| APA | Chen, Weidong.,Yu, Haibo.,Wu, Guotao.,He, Teng.,Li, Zhao.,...&Chen, Ping.(2016).Ammonium aminodiboranate: a long-sought isomer of diammoniate of diborane and ammonia borane dimer.Chemistry-a european journal,22(23),7727-7729. |
| MLA | Chen, Weidong,et al."Ammonium aminodiboranate: a long-sought isomer of diammoniate of diborane and ammonia borane dimer".Chemistry-a european journal 22.23(2016):7727-7729. |
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来源：中国科学院大学
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