Visible-light-driven photocatalytic activation of inert sulfur ylides for 3-acyl oxindole synthesis
文献类型：期刊论文
| 作者 | Xia, Xu-Dong1; Lu, Liang-Qiu1; Liu, Wen-Qiang2,3; Chen, Dong-Zhen1; Zheng, Yu-Han1; Wu, Li-Zhu2,3; Xiao, Wen-Jing1 |
| 刊名 | Chemistry-a european journal
 |
| 出版日期 | 2016-06-13 |
| 卷号 | 22期号:25页码:8432-8437 |
| 关键词 | C-h functionalization Oxindoles Photocatalysis Sulfur ylides Visible light |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201600871 |
| 通讯作者 | Wu, li-zhu(lzwu@mail.ipc.ac.cn) ; Xiao, wen-jing(wxiao@mail.ccnu.edu.cn) |
| 英文摘要 | Bicarbonyl-substituted sulfur ylide is a useful, but inert reagent in organic synthesis. usually, harsh reaction conditions are required for its transformation. for the first time, it was demonstrated that a new, visible-light photoredox catalytic annulation of sulfur ylides under extremely mild conditions, permits the synthesis of oxindole derivatives in high selectivities and efficiencies. the key to its success is the photocatalytic single-electron-transfer (set) oxidation of the inert amide and acyl-stabilized sulfur ylides to reactive radical cations, which easily proceeds with intramolecular c-h functionalization to give the final products. |
| WOS关键词 | TANDEM RADICAL CYCLIZATION ; PHOTOREDOX CATALYSIS ; N-ARYLACRYLAMIDES ; ORGANIC-SYNTHESIS ; SULFONIUM YLIDES ; CASCADE REACTIONS ; GOLD ; EFFICIENT ; CYCLOPROPANATION ; CYCLOADDITION |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| 语种 | 英语 |
| WOS记录号 | WOS:000380270100002 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2374522 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Wu, Li-Zhu; Xiao, Wen-Jing |
| 作者单位 | 1.Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Coll Chem, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China 2.Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Xu-Dong,Lu, Liang-Qiu,Liu, Wen-Qiang,et al. Visible-light-driven photocatalytic activation of inert sulfur ylides for 3-acyl oxindole synthesis[J]. Chemistry-a european journal,2016,22(25):8432-8437. |
| APA | Xia, Xu-Dong.,Lu, Liang-Qiu.,Liu, Wen-Qiang.,Chen, Dong-Zhen.,Zheng, Yu-Han.,...&Xiao, Wen-Jing.(2016).Visible-light-driven photocatalytic activation of inert sulfur ylides for 3-acyl oxindole synthesis.Chemistry-a european journal,22(25),8432-8437. |
| MLA | Xia, Xu-Dong,et al."Visible-light-driven photocatalytic activation of inert sulfur ylides for 3-acyl oxindole synthesis".Chemistry-a european journal 22.25(2016):8432-8437. |
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来源：中国科学院大学
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